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• W3028338492 startingPage "5794" @default.
• W3028338492 abstract "Abstract Substituted tetrahedranes offer exceptional carbon bases with the gas‐phase proton affinities (PAs) up to 356 kcal mol −1 , due to the strain‐induced ring opening upon protonation. Additional tetrahedrane moieties exert a dramatic basicity amplification to PAs reaching 600 kcal mol −1 , being the strongest organic superbases reported, clearly surpassing the proposed limit of achievable basicities (Angew. Chem. Int. Ed. 2015, 54, 9262). However, because protonation/deprotonation of these compounds is not reversible, PAs of the opened‐cage isomers were calculated which were lower than the basiciy limit." @default.
• W3028338492 created "2020-05-29" @default.
• W3028338492 creator A5051259067 @default.
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• W3028338492 date "2020-05-20" @default.
• W3028338492 modified "2023-10-17" @default.
• W3028338492 title "Is It Possible to Achieve Organic Superbases beyond the Basicity Limit Using Tetrahedrane Scaffolds?" @default.
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• W3028338492 doi "https://doi.org/10.1002/slct.202001407" @default.
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