Matches in SemOpenAlex for { <https://semopenalex.org/work/W3029022488> ?p ?o ?g. }
- W3029022488 endingPage "125681" @default.
- W3029022488 startingPage "125681" @default.
- W3029022488 abstract "Abstract Core-shell structured hybrid octahedron, which contained a Fe-based nanoparticle core (Fe/Fe3C) and a graphitized porous carbon (PC) shell (Fe/Fe3C@PC), prepared through one-pot pyrolysis using MIL-101(Fe) as the sacrificial template, was used as a novel catalyst for the degradation of sulfamethazine (SMT) by heterogeneous electro-Fenton (Hetero-EF). Fe/Fe3C@PC outperformed common heterogeneous catalysts such as Fe0, Fe3O4 and Fe2O3 due to the synergistic effect between Fe/Fe3C nanoparticles and PC. The rate constant for SMT degradation in the Hetero-EF process was 7.17-folds of that in the heterogeneous Fenton (Hetero-F) process. The plausible catalytic mechanism and degradation pathway for mineralization of SMT by this Hetero-EF process were proposed, confirming the main role of surface-bound hydroxyl radical ( OHads) oxidation. Moreover, internal-micro-electrolysis (IME)-enhanced Hetero-EF reaction was verified by experiments and density functional theory (DFT) calculations. Fe/Fe3C@PC could be easily recycled due to magnetism and well recovered via a simple thermal treatment in H2 atmosphere. This work enlightened metal–organic frameworks (MOFs) derived core–shell structured hybrids to be ultra-efficient heterogeneous catalysts and their catalytic mechanism promoting promising utilization in the Hetero-EF process for organic pollutants removal." @default.
- W3029022488 created "2020-06-05" @default.
- W3029022488 creator A5013289651 @default.
- W3029022488 creator A5024384626 @default.
- W3029022488 creator A5035075036 @default.
- W3029022488 creator A5044263966 @default.
- W3029022488 creator A5074678074 @default.
- W3029022488 date "2020-10-01" @default.
- W3029022488 modified "2023-10-18" @default.
- W3029022488 title "Internal-micro-electrolysis-enhanced heterogeneous electro-Fenton process catalyzed by Fe/Fe3C@PC core–shell hybrid for sulfamethazine degradation" @default.
- W3029022488 cites W1123190761 @default.
- W3029022488 cites W1965937227 @default.
- W3029022488 cites W1968322592 @default.
- W3029022488 cites W1976560488 @default.
- W3029022488 cites W1978240648 @default.
- W3029022488 cites W1993054776 @default.
- W3029022488 cites W1994451264 @default.
- W3029022488 cites W1997858197 @default.
- W3029022488 cites W2007661885 @default.
- W3029022488 cites W2014482480 @default.
- W3029022488 cites W2034277923 @default.
- W3029022488 cites W2040030673 @default.
- W3029022488 cites W2047491784 @default.
- W3029022488 cites W2058010120 @default.
- W3029022488 cites W2060642913 @default.
- W3029022488 cites W2079613864 @default.
- W3029022488 cites W2080824589 @default.
- W3029022488 cites W2082179062 @default.
- W3029022488 cites W2090041909 @default.
- W3029022488 cites W2100838242 @default.
- W3029022488 cites W2101866328 @default.
- W3029022488 cites W2110864332 @default.
- W3029022488 cites W2156142652 @default.
- W3029022488 cites W2279785115 @default.
- W3029022488 cites W2315776822 @default.
- W3029022488 cites W2331310872 @default.
- W3029022488 cites W2345915222 @default.
- W3029022488 cites W2443933168 @default.
- W3029022488 cites W2514139663 @default.
- W3029022488 cites W2519522313 @default.
- W3029022488 cites W2551377048 @default.
- W3029022488 cites W2555033260 @default.
- W3029022488 cites W2602645936 @default.
- W3029022488 cites W2606058169 @default.
- W3029022488 cites W2614941226 @default.
- W3029022488 cites W2617122582 @default.
- W3029022488 cites W2617787895 @default.
- W3029022488 cites W2669679103 @default.
- W3029022488 cites W2676123895 @default.
- W3029022488 cites W2770586370 @default.
- W3029022488 cites W2777981954 @default.
- W3029022488 cites W2782373065 @default.
- W3029022488 cites W2790464555 @default.
- W3029022488 cites W2799316305 @default.
- W3029022488 cites W2799765798 @default.
- W3029022488 cites W2800032317 @default.
- W3029022488 cites W2802615836 @default.
- W3029022488 cites W2811411974 @default.
- W3029022488 cites W2885862988 @default.
- W3029022488 cites W2886589782 @default.
- W3029022488 cites W2886984026 @default.
- W3029022488 cites W2903455900 @default.
- W3029022488 cites W2908169233 @default.
- W3029022488 cites W2912705823 @default.
- W3029022488 cites W2922395279 @default.
- W3029022488 cites W2936657119 @default.
- W3029022488 cites W2951012947 @default.
- W3029022488 cites W2953950326 @default.
- W3029022488 cites W2960775064 @default.
- W3029022488 cites W2964950528 @default.
- W3029022488 cites W2967195464 @default.
- W3029022488 cites W2977777077 @default.
- W3029022488 cites W2979575198 @default.
- W3029022488 cites W2985704251 @default.
- W3029022488 cites W2989748895 @default.
- W3029022488 cites W966624069 @default.
- W3029022488 doi "https://doi.org/10.1016/j.cej.2020.125681" @default.
- W3029022488 hasPublicationYear "2020" @default.
- W3029022488 type Work @default.
- W3029022488 sameAs 3029022488 @default.
- W3029022488 citedByCount "98" @default.
- W3029022488 countsByYear W30290224882020 @default.
- W3029022488 countsByYear W30290224882021 @default.
- W3029022488 countsByYear W30290224882022 @default.
- W3029022488 countsByYear W30290224882023 @default.
- W3029022488 crossrefType "journal-article" @default.
- W3029022488 hasAuthorship W3029022488A5013289651 @default.
- W3029022488 hasAuthorship W3029022488A5024384626 @default.
- W3029022488 hasAuthorship W3029022488A5035075036 @default.
- W3029022488 hasAuthorship W3029022488A5044263966 @default.
- W3029022488 hasAuthorship W3029022488A5074678074 @default.
- W3029022488 hasConcept C111919701 @default.
- W3029022488 hasConcept C127413603 @default.
- W3029022488 hasConcept C147789679 @default.
- W3029022488 hasConcept C159985019 @default.
- W3029022488 hasConcept C161790260 @default.
- W3029022488 hasConcept C163127949 @default.
- W3029022488 hasConcept C17525397 @default.