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- W3029585702 abstract "Increasing antimony (Sb) pollution has posed severe health threats to human beings and the environment. In the study, iron-based metal-organic framework Fe-MIL-88B was synthesized at low temperature (40 °C) via ethanol as solvent. And the removal of Sb(III) and Sb(V) by using Fe-MIL-88B were investigated systematically with the effects of pH, adsorbent dosages, adsorption time, initial concentration and co-existing anions. Rapid adsorption kinetics and high adsorption capacities g− g− were obtained. Sb was also removed by Fe-MIL-88B from natural water successfully. And the concentrations of residual Sb(III) and Sb(V) were below 5 μg L−1, meeting the drinking water standard. New insights into the possible removal mechanisms were provided that the coordination between Fe3-μ3-oxo clusters of Fe-MIL-88B and Sb attributed to the adsorption of Sb. And more active adsorption sites were generated by in-situ formed hydrous ferric oxide (HFO) on the surface of the adsorbent, which also improved the removal of Sb. And the mechanisms were supported by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) characterizations. The results revealed that Fe-MIL-88B is a promising and efficient adsorbent for Sb removal in practical applications." @default.
- W3029585702 created "2020-06-05" @default.
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- W3029585702 date "2020-10-01" @default.
- W3029585702 modified "2023-10-14" @default.
- W3029585702 title "New insights into the removal of antimony from water using an iron-based metal-organic framework: Adsorption behaviors and mechanisms" @default.
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- W3029585702 doi "https://doi.org/10.1016/j.colsurfa.2020.125054" @default.
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