Matches in SemOpenAlex for { <https://semopenalex.org/work/W3029722256> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W3029722256 endingPage "118537" @default.
- W3029722256 startingPage "118537" @default.
- W3029722256 abstract "In this paper, six phosphorescent Cu(I) complexes with three diamine ligands and two phosphorous ligands were prepared. Detailed discussion was performed on these complexes, including single crystals, quantum mechanics theoretical calculation, absorption spectra, emission spectra, emission quantum yields and excited state decay dynamics. Large conjugation planes and π-π stacking were found in these complexes. Their emission was originated from MLCT excited state. Long-lived emissive center was observed due to this MLCT-based decay and the help from π-π stacking. Such long-lived emissive state and the large conjugation planes in these complexes offered enough collision probability with O2 molecules, making themselves potential oxygen sensing probes. These six complexes were then doped into silica supporting matrix MCM-41 spheres. The resulting composite samples and their emission sensing response towards O2 were discussed in detail. The optimal sample showed sensitivity as high as 7.80 with response time of 14 s. A careful discussion between Cu(I) complex molecular structure and sensing performance was performed. It was concluded that both a long lifetime and a large conjugation plane lead to improved sensing sensitivity since they increased the collision probability with O2 molecules. On the other hand, it was found that both sensing response and recovery times were mainly controlled by O2 diffusion in supporting matrix." @default.
- W3029722256 created "2020-06-05" @default.
- W3029722256 creator A5044082365 @default.
- W3029722256 date "2020-10-01" @default.
- W3029722256 modified "2023-09-26" @default.
- W3029722256 title "Improving oxygen sensing performance via inner-molecular π-π stacking in a series of phosphorescent Cu(I) complexes" @default.
- W3029722256 cites W1965396819 @default.
- W3029722256 cites W1978965445 @default.
- W3029722256 cites W2001168587 @default.
- W3029722256 cites W2003461336 @default.
- W3029722256 cites W2007111400 @default.
- W3029722256 cites W2007819591 @default.
- W3029722256 cites W2016188652 @default.
- W3029722256 cites W2048276875 @default.
- W3029722256 cites W2048348738 @default.
- W3029722256 cites W2065863985 @default.
- W3029722256 cites W2093862284 @default.
- W3029722256 cites W2102077261 @default.
- W3029722256 cites W2118587677 @default.
- W3029722256 cites W2135427658 @default.
- W3029722256 cites W2521221679 @default.
- W3029722256 cites W2588741576 @default.
- W3029722256 cites W2763038572 @default.
- W3029722256 cites W2913288471 @default.
- W3029722256 cites W2949242362 @default.
- W3029722256 doi "https://doi.org/10.1016/j.saa.2020.118537" @default.
- W3029722256 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32502810" @default.
- W3029722256 hasPublicationYear "2020" @default.
- W3029722256 type Work @default.
- W3029722256 sameAs 3029722256 @default.
- W3029722256 citedByCount "3" @default.
- W3029722256 countsByYear W30297222562021 @default.
- W3029722256 countsByYear W30297222562022 @default.
- W3029722256 crossrefType "journal-article" @default.
- W3029722256 hasAuthorship W3029722256A5044082365 @default.
- W3029722256 hasConcept C119824511 @default.
- W3029722256 hasConcept C120665830 @default.
- W3029722256 hasConcept C121332964 @default.
- W3029722256 hasConcept C125287762 @default.
- W3029722256 hasConcept C1276947 @default.
- W3029722256 hasConcept C159467904 @default.
- W3029722256 hasConcept C159985019 @default.
- W3029722256 hasConcept C178790620 @default.
- W3029722256 hasConcept C181500209 @default.
- W3029722256 hasConcept C181817918 @default.
- W3029722256 hasConcept C184779094 @default.
- W3029722256 hasConcept C185592680 @default.
- W3029722256 hasConcept C192562407 @default.
- W3029722256 hasConcept C32909587 @default.
- W3029722256 hasConcept C33347731 @default.
- W3029722256 hasConcept C41999313 @default.
- W3029722256 hasConcept C4839761 @default.
- W3029722256 hasConcept C75473681 @default.
- W3029722256 hasConcept C91881484 @default.
- W3029722256 hasConcept C96141758 @default.
- W3029722256 hasConceptScore W3029722256C119824511 @default.
- W3029722256 hasConceptScore W3029722256C120665830 @default.
- W3029722256 hasConceptScore W3029722256C121332964 @default.
- W3029722256 hasConceptScore W3029722256C125287762 @default.
- W3029722256 hasConceptScore W3029722256C1276947 @default.
- W3029722256 hasConceptScore W3029722256C159467904 @default.
- W3029722256 hasConceptScore W3029722256C159985019 @default.
- W3029722256 hasConceptScore W3029722256C178790620 @default.
- W3029722256 hasConceptScore W3029722256C181500209 @default.
- W3029722256 hasConceptScore W3029722256C181817918 @default.
- W3029722256 hasConceptScore W3029722256C184779094 @default.
- W3029722256 hasConceptScore W3029722256C185592680 @default.
- W3029722256 hasConceptScore W3029722256C192562407 @default.
- W3029722256 hasConceptScore W3029722256C32909587 @default.
- W3029722256 hasConceptScore W3029722256C33347731 @default.
- W3029722256 hasConceptScore W3029722256C41999313 @default.
- W3029722256 hasConceptScore W3029722256C4839761 @default.
- W3029722256 hasConceptScore W3029722256C75473681 @default.
- W3029722256 hasConceptScore W3029722256C91881484 @default.
- W3029722256 hasConceptScore W3029722256C96141758 @default.
- W3029722256 hasLocation W30297222561 @default.
- W3029722256 hasLocation W30297222562 @default.
- W3029722256 hasOpenAccess W3029722256 @default.
- W3029722256 hasPrimaryLocation W30297222561 @default.
- W3029722256 hasRelatedWork W1661706694 @default.
- W3029722256 hasRelatedWork W2016755079 @default.
- W3029722256 hasRelatedWork W2042015852 @default.
- W3029722256 hasRelatedWork W2095113074 @default.
- W3029722256 hasRelatedWork W2099782517 @default.
- W3029722256 hasRelatedWork W2112106051 @default.
- W3029722256 hasRelatedWork W2384388808 @default.
- W3029722256 hasRelatedWork W2470261725 @default.
- W3029722256 hasRelatedWork W4250571304 @default.
- W3029722256 hasRelatedWork W56419567 @default.
- W3029722256 hasVolume "239" @default.
- W3029722256 isParatext "false" @default.
- W3029722256 isRetracted "false" @default.
- W3029722256 magId "3029722256" @default.
- W3029722256 workType "article" @default.