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• W3030018408 startingPage "4483" @default.
• W3030018408 abstract "We herein report a versatile, regio- and enantioselective palladium-catalyzed tandem allylic substitution powered by a chiral bisphosphorus ligand WingPhos with the palladium loading as low as 0.1 mol %, forming a series of chiral vinyl-substituted heterocycles, including tetrahydroquinoxalines, piperazines, dihydro-2H-benzo[b][1,4]-oxazines, and morpholines, in exellent ee’s and yields. The protocol features readily available starting materials, mild reaction conditions, and a broad substrate scope. Mechanistic investigation supports a tandem allylic substitution process." @default.
• W3030018408 created "2020-06-05" @default.
• W3030018408 creator A5019725336 @default.
• W3030018408 creator A5028023634 @default.
• W3030018408 date "2020-05-26" @default.
• W3030018408 modified "2023-10-16" @default.
• W3030018408 title "A Versatile Synthesis of Vinyl-Substituted Heterocycles via Regio- and Enantioselective Pd-Catalyzed Tandem Allylic Substitution" @default.
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• W3030018408 doi "https://doi.org/10.1021/acs.orglett.0c01490" @default.
• W3030018408 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32453581" @default.
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