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- W3030444013 abstract "メソ多孔性シリカであるFSM-16の骨格にA1を導入したAl-FSM-16，およびシリル化処理を施したTMS中FSM-16を調製し，その細孔構造と吸着特性について，窒素および二酸化炭素をプローブ分子として検討した．Al-FSM-16の比表面積は470m2・g-1，FSM-16にくらべ半分程度となったが，二酸化炭素と窒素との混合気体を吸着させると，0.2～0.3MPaの圧力領域で，二酸化炭素の分離係数がFSM-16にくらべ2倍以上大きくなった．これは，Al導入にともない負電荷を補償するために存在するNa+へ，二酸化炭素が選択的に吸着したためである．FSM中16のシリル化では，メソ孔内表面の82%がTMS基により被覆され，細孔径が2.8nmから2.3nmへ減少した．TMS中FSM-16への二酸化炭素の吸着量は，FSM-16にくらべ，自由Si0H基がシリル化により減少したため，吸着温度273Kで半分程度となった．" @default.
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- W3030444013 date "2001-01-01" @default.
- W3030444013 modified "2023-09-27" @default.
- W3030444013 title "Formation of Ordered Structure in Liquid Phase and Its Use for Materials Design. The Control of Pore Structure and Adsorption Characteristics of Mesoporous Silicas." @default.
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- W3030444013 doi "https://doi.org/10.1252/kakoronbunshu.27.719" @default.
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