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• W3030897267 abstract "Abstract The gas‐phase extrusion–insertion reactions of the copper complex [bathophenanthroline (Bphen)Cu I (O 2 CC 6 H 5 )] 2− , generated via electrospray ionization, was studied in a linear ion trap mass spectrometer with the combination of collision‐induced dissociation (CID) and ion‐molecule reaction (IMR) events. Multistage mass spectrometry (MS n ) experiments and density functional theory (DFT) demonstrated that extrusion of carbon dioxide from [(Bphen)Cu(O 2 CC 6 H 5 )] 2− (CID) gives the organometallic intermediate [(Bphen)Cu(C 6 H 5 )] 2− , which subsequently reacts with carbon disulfide (IMR) via insertion to yield [(Bphen)Cu (SC(S)C 6 H 5 )] 2− . The fragmentation of the product ion resulted in the formation of [Bphen] 2− , [(Bphen)Cu] − and C 6 H 5 CS 2 − under CID conditions. The formation of the latter two charge separation products thus provides evidence of C–C bond formation in the IMR step. Although analogous studies with isocyanate, which is isoelectronic with CS 2 , showed a poor reactivity in the gas phase, the mechanistic understanding obtained from these model studies encourages future development of a solution phase protocol for the synthesis of amides from carboxylic acids and isocyanates mediated by copper(I) complexes." @default.
• W3030897267 created "2020-06-05" @default.
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• W3030897267 date "2020-06-24" @default.
• W3030897267 modified "2023-09-29" @default.
• W3030897267 title "Gas‐phase studies of copper(I)‐mediated CO₂ extrusion followed by insertion of the heterocumulenes CS₂ or phenylisocyanate" @default.
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• W3030897267 doi "https://doi.org/10.1002/jms.4579" @default.
• W3030897267 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32578305" @default.
• W3030897267 hasPublicationYear "2020" @default.
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