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• W3030942335 abstract "The metal–support interaction offers electronic, compositional, and geometric effects that can enhance the catalytic activity and stability. Herein, a performance‐enhanced electrocatalyst of Pd nanoparticles loaded on a hybrid catalytic support comprised of MXene (Ti 3 C 2 T x ) and carbon nanotube (CNT) is demonstrated. Such a hybrid catalyst enhances durability and improves both oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) activities compared with the Pd/C catalysts. The mass specific activity and specific activity of the Pd/Ti 3 C 2 T x –CNT catalyst are 4.4 and 3.3 times that of Pd/C for ORR, respectively. The peak power density of a alkaline anion exchange membrane fuel cell (AAEMFC) based on the Pd/Ti 3 C 2 T x –CNT (1:2) cathode achieves 48 mW cm −2 at 60 °C. Furthermore, Pd/Ti 3 C 2 T x –CNT also exhibits rapid HER kinetics with a low overpotential of 158 mV at 10 mA cm −2 and a Tafel slope of 50 mV dec −1 . Pd/Ti 3 C 2 T x –CNT also provides good stability after 1000 cycles. These remarkable catalytic performances are attributed to the role of Ti 3 C 2 T x and CNT by enhancing the catalytic activity surface area and rapid mass/charge transfer due to the synergistic effect between Pd and Ti 3 C 2 T x –CNT." @default.
• W3030942335 created "2020-06-05" @default.
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• W3030942335 date "2020-06-08" @default.
• W3030942335 modified "2023-10-09" @default.
• W3030942335 title "The High‐Performance Bifunctional Catalyst Pd/Ti ₃ C ₂ T _<i>x</i> –Carbon Nanotube for Oxygen Reduction Reaction and Hydrogen Evolution Reaction in Alkaline Medium" @default.
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• W3030942335 doi "https://doi.org/10.1002/ente.202000306" @default.
• W3030942335 hasPublicationYear "2020" @default.
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