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- W3031387258 endingPage "11513" @default.
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- W3031387258 abstract "The direct and chemoselective conversion of the carbon–metal bond of gem-dimetallic reagents enables rapid and sequential formation of multiple carbon–carbon and carbon–heteroatom bonds, thus representing a powerful method for efficiently increasing structural complexity. Herein, we report a visible-light-induced, nickel-catalyzed, chemoselective cross-coupling reaction between gem-borazirconocene alkanes and diverse aryl halides, affording a wide range of alkyl Bpin derivatives in high yields with excellent regioselectivity. This practical method features attractively simple reaction conditions and a broad substrate scope. Additionally, we systematically investigated a Bpin-directed chain walking process underlying the regioselectivity of alkylzirconocenes, thus uncovering the mechanism of the remote functionalization of internal olefins achieved with our method. Finally, DFT calculations indicate that the high regioselectivity of this reaction originates from the directing effect of the Bpin group." @default.
- W3031387258 created "2020-06-05" @default.
- W3031387258 creator A5014135146 @default.
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- W3031387258 creator A5031249029 @default.
- W3031387258 creator A5060061835 @default.
- W3031387258 creator A5061788948 @default.
- W3031387258 date "2020-06-04" @default.
- W3031387258 modified "2023-10-09" @default.
- W3031387258 title "Chemoselective Cross-Coupling of <i>gem</i>-Borazirconocene Alkanes with Aryl Halides" @default.
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