FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3031613721> ?p ?o ?g. }

• W3031613721 endingPage "100544" @default.
• W3031613721 startingPage "100544" @default.
• W3031613721 abstract "Self-assembled monolayers (SAMs) prepared by adsorption of 4-Fluorobenzenethiol (p-FBT) and 4-Fluorobenzenemethanethiol (p-FBMT) on Au(111) substrates with different immersion times (ITs) at room temperature have been characterized using scanning tunneling microscopy (STM). The resulting p-FBT and p-FBMT monolayers showed substantial differences concerning their adlayer SAM structure and surface morphology. The structural quality of p-FBT-SAMs was found to depend significantly on the preparation conditions such as the IT. At short IT of ~3 h, the p-FBT-SAMs were found to mainly include disordered phase (α-phase) between the surrounding areas of the gold islands. With increasing IT, a gradual phase transition from the disordered phase (α) into ordered one (β-phase) was observed. Consequently, increasing the IT to ~ 24 h resulted in the formation of well-defined and highly ordered β-phase that is characterized by the commensurate (83×23)R30∘superstructure. In contrast to the p-FBT-SAMs, a full-coverage and close packed monolayers were formed in p-FBMT-SAMs only after very short IT of ~1 min. The upright-standing p-FBMT molecules were found to form a (3×3)R30∘structure. Despite the absence of a periodic variation in the height of the molecules within the molecular domains, we proposed a larger (23×3)R30∘unit cell containing two inequivalent p-FBMT molecules arranged in a herringbone-type structure instead of the smaller (3×3)R30∘unit cell. The considerable difference in the behavior of these closely related molecules which differ only in their structure (an additional methyl group between benzene and S group in p-FBMT), clarifies the delicate balance of the factors which define the energy and the structure of thiol SAMs." @default.
• W3031613721 created "2020-06-05" @default.
• W3031613721 creator A5036970887 @default.
• W3031613721 creator A5071788351 @default.
• W3031613721 date "2020-09-01" @default.
• W3031613721 modified "2023-09-27" @default.
• W3031613721 title "Influence of an alkyl spacer on the formation and structure of 4-Fluorobenzenethiol and 4-Fluorobenzenemethanethiol self-assembled monolayers on Au(111)" @default.
• W3031613721 cites W1972349516 @default.
• W3031613721 cites W1972884636 @default.
• W3031613721 cites W1974185323 @default.
• W3031613721 cites W1974750028 @default.
• W3031613721 cites W1974872096 @default.
• W3031613721 cites W1974889287 @default.
• W3031613721 cites W1975423947 @default.
• W3031613721 cites W1977590126 @default.
• W3031613721 cites W1986752938 @default.
• W3031613721 cites W1989172362 @default.
• W3031613721 cites W2000362175 @default.
• W3031613721 cites W2000479654 @default.
• W3031613721 cites W2000800562 @default.
• W3031613721 cites W2001732438 @default.
• W3031613721 cites W2003924208 @default.
• W3031613721 cites W2003982588 @default.
• W3031613721 cites W2005231224 @default.
• W3031613721 cites W2008276228 @default.
• W3031613721 cites W2009245940 @default.
• W3031613721 cites W2012904250 @default.
• W3031613721 cites W2013026314 @default.
• W3031613721 cites W2014661497 @default.
• W3031613721 cites W2017371196 @default.
• W3031613721 cites W2019550499 @default.
• W3031613721 cites W2021937056 @default.
• W3031613721 cites W2024330717 @default.
• W3031613721 cites W2028047218 @default.
• W3031613721 cites W2031183081 @default.
• W3031613721 cites W2032915139 @default.
• W3031613721 cites W2036122637 @default.
• W3031613721 cites W2037222272 @default.
• W3031613721 cites W2038820537 @default.
• W3031613721 cites W2041646448 @default.
• W3031613721 cites W2044360398 @default.
• W3031613721 cites W2045008379 @default.
• W3031613721 cites W2045442331 @default.
• W3031613721 cites W2045532248 @default.
• W3031613721 cites W2047952781 @default.
• W3031613721 cites W2054830976 @default.
• W3031613721 cites W2055721836 @default.
• W3031613721 cites W2059543240 @default.
• W3031613721 cites W2063752296 @default.
• W3031613721 cites W2067124125 @default.
• W3031613721 cites W2071167932 @default.
• W3031613721 cites W2074066890 @default.
• W3031613721 cites W2074741141 @default.
• W3031613721 cites W2075934346 @default.
• W3031613721 cites W2077623481 @default.
• W3031613721 cites W2079884685 @default.
• W3031613721 cites W2081627119 @default.
• W3031613721 cites W2081828769 @default.
• W3031613721 cites W2087092966 @default.
• W3031613721 cites W2087672250 @default.
• W3031613721 cites W2089551376 @default.
• W3031613721 cites W2092023884 @default.
• W3031613721 cites W2094100179 @default.
• W3031613721 cites W2094258891 @default.
• W3031613721 cites W2104785971 @default.
• W3031613721 cites W2114677196 @default.
• W3031613721 cites W2121066654 @default.
• W3031613721 cites W2153367590 @default.
• W3031613721 cites W2157799320 @default.
• W3031613721 cites W2160707406 @default.
• W3031613721 cites W2166081351 @default.
• W3031613721 cites W2166806803 @default.
• W3031613721 cites W2272496178 @default.
• W3031613721 cites W2317047180 @default.
• W3031613721 cites W2317502703 @default.
• W3031613721 cites W2326897435 @default.
• W3031613721 cites W2329856692 @default.
• W3031613721 cites W2436393780 @default.
• W3031613721 cites W2473500031 @default.
• W3031613721 cites W2526745698 @default.
• W3031613721 cites W2576932699 @default.
• W3031613721 cites W2914545500 @default.
• W3031613721 cites W2964711265 @default.
• W3031613721 cites W2979457053 @default.
• W3031613721 cites W2996610301 @default.
• W3031613721 cites W918510825 @default.
• W3031613721 doi "https://doi.org/10.1016/j.surfin.2020.100544" @default.
• W3031613721 hasPublicationYear "2020" @default.
• W3031613721 type Work @default.
• W3031613721 sameAs 3031613721 @default.
• W3031613721 citedByCount "5" @default.
• W3031613721 countsByYear W30316137212020 @default.
• W3031613721 countsByYear W30316137212022 @default.
• W3031613721 countsByYear W30316137212023 @default.
• W3031613721 crossrefType "journal-article" @default.
• W3031613721 hasAuthorship W3031613721A5036970887 @default.
• W3031613721 hasAuthorship W3031613721A5071788351 @default.
• W3031613721 hasConcept C111368507 @default.

• next