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- W3031697776 abstract "The sulfone functional group has a strong capacity to direct the asymmetric transfer hydrogenation (ATH) of ketones in the presence of [(arene)Ru(TsDPEN)H] complexes by adopting a position distal to the η6-arene ring. This preference provides a means for the prediction of the sense of asymmetric reduction. The sulfone group also facilitates the formation of a range of reduction substrates, and its ready removal provides a route to enantiomerically enriched alcohols that would otherwise be extremely difficult to prepare by direct ATH of the corresponding ketones." @default.
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- W3031697776 date "2020-07-01" @default.
- W3031697776 modified "2023-10-18" @default.
- W3031697776 title "Sulfone Group as a Versatile and Removable Directing Group for Asymmetric Transfer Hydrogenation of Ketones" @default.
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- W3031697776 doi "https://doi.org/10.1002/anie.202004658" @default.
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