Matches in SemOpenAlex for { <https://semopenalex.org/work/W303254251> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W303254251 abstract "In the classical approach to unimolecular reactions developed by Slater, it is assumed that the motion along the reaction coordinate q is determined by a superpositioning of the contributions to q from the coordinates of the individual harmonic vibrational modes of the molecule. In this case, a reaction is possible at points of beating along q and the average beat frequency determines the preexponential factor k/sub 0/ in the Arrhenius expression for the rate constant. However, in a number of cases involving the dissociation reactions of complex molecules, a simpler approach may be proposed in which not only k/sub 0/ but also the value of the activation energy E/sub 0/ can be determined experimentally using IR spectroscopy. In the present paper a generalization is proposed of an approach to a case where the bond which is broken in reaction participates in several normal vibrational modes of the initial molecule." @default.
- W303254251 created "2016-06-24" @default.
- W303254251 creator A5013911807 @default.
- W303254251 creator A5022586329 @default.
- W303254251 creator A5031219110 @default.
- W303254251 creator A5063775987 @default.
- W303254251 date "1983-02-01" @default.
- W303254251 modified "2023-09-23" @default.
- W303254251 title "Determination of the activation energies of unimolecular dissociation reactions by means of IR spectroscopy. N-nitrodimethylamine" @default.
- W303254251 hasPublicationYear "1983" @default.
- W303254251 type Work @default.
- W303254251 sameAs 303254251 @default.
- W303254251 citedByCount "0" @default.
- W303254251 crossrefType "journal-article" @default.
- W303254251 hasAuthorship W303254251A5013911807 @default.
- W303254251 hasAuthorship W303254251A5022586329 @default.
- W303254251 hasAuthorship W303254251A5031219110 @default.
- W303254251 hasAuthorship W303254251A5063775987 @default.
- W303254251 hasConcept C102931765 @default.
- W303254251 hasConcept C121332964 @default.
- W303254251 hasConcept C147597530 @default.
- W303254251 hasConcept C147789679 @default.
- W303254251 hasConcept C148898269 @default.
- W303254251 hasConcept C153642686 @default.
- W303254251 hasConcept C178790620 @default.
- W303254251 hasConcept C184779094 @default.
- W303254251 hasConcept C18553476 @default.
- W303254251 hasConcept C185592680 @default.
- W303254251 hasConcept C24123453 @default.
- W303254251 hasConcept C32891209 @default.
- W303254251 hasConcept C32909587 @default.
- W303254251 hasConcept C40934718 @default.
- W303254251 hasConcept C62396407 @default.
- W303254251 hasConcept C62520636 @default.
- W303254251 hasConcept C86183883 @default.
- W303254251 hasConcept C93391505 @default.
- W303254251 hasConcept C95121573 @default.
- W303254251 hasConcept C97355855 @default.
- W303254251 hasConceptScore W303254251C102931765 @default.
- W303254251 hasConceptScore W303254251C121332964 @default.
- W303254251 hasConceptScore W303254251C147597530 @default.
- W303254251 hasConceptScore W303254251C147789679 @default.
- W303254251 hasConceptScore W303254251C148898269 @default.
- W303254251 hasConceptScore W303254251C153642686 @default.
- W303254251 hasConceptScore W303254251C178790620 @default.
- W303254251 hasConceptScore W303254251C184779094 @default.
- W303254251 hasConceptScore W303254251C18553476 @default.
- W303254251 hasConceptScore W303254251C185592680 @default.
- W303254251 hasConceptScore W303254251C24123453 @default.
- W303254251 hasConceptScore W303254251C32891209 @default.
- W303254251 hasConceptScore W303254251C32909587 @default.
- W303254251 hasConceptScore W303254251C40934718 @default.
- W303254251 hasConceptScore W303254251C62396407 @default.
- W303254251 hasConceptScore W303254251C62520636 @default.
- W303254251 hasConceptScore W303254251C86183883 @default.
- W303254251 hasConceptScore W303254251C93391505 @default.
- W303254251 hasConceptScore W303254251C95121573 @default.
- W303254251 hasConceptScore W303254251C97355855 @default.
- W303254251 hasLocation W3032542511 @default.
- W303254251 hasOpenAccess W303254251 @default.
- W303254251 hasPrimaryLocation W3032542511 @default.
- W303254251 hasRelatedWork W1990621195 @default.
- W303254251 hasRelatedWork W1996142220 @default.
- W303254251 hasRelatedWork W1998928230 @default.
- W303254251 hasRelatedWork W1999735104 @default.
- W303254251 hasRelatedWork W2004397879 @default.
- W303254251 hasRelatedWork W2042098512 @default.
- W303254251 hasRelatedWork W2045318428 @default.
- W303254251 hasRelatedWork W2071626042 @default.
- W303254251 hasRelatedWork W2085367471 @default.
- W303254251 hasRelatedWork W2087947987 @default.
- W303254251 hasRelatedWork W2114147579 @default.
- W303254251 hasRelatedWork W2120444403 @default.
- W303254251 hasRelatedWork W2243617655 @default.
- W303254251 hasRelatedWork W2586964981 @default.
- W303254251 hasRelatedWork W2587854738 @default.
- W303254251 hasRelatedWork W2953350414 @default.
- W303254251 hasRelatedWork W2970256228 @default.
- W303254251 hasRelatedWork W3004967168 @default.
- W303254251 hasRelatedWork W3182123566 @default.
- W303254251 hasRelatedWork W2496066079 @default.
- W303254251 isParatext "false" @default.
- W303254251 isRetracted "false" @default.
- W303254251 magId "303254251" @default.
- W303254251 workType "article" @default.