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- W3032962016 abstract "Abstract Herein, we report the fabrication of rGO@α-MnO2/rGO@δ-MnO2 nanohybrid containing bio-derived water dispersed polyurethane (PU) nanocomposite (PUNH). Three nanocomposites of PU were fabricated with 0.5, 1.0 and 1.5 weight percentages of rGO@α-MnO2/rGO@δ-MnO2 and characterized by using various techniques including FTIR, XRD, BET, CV, FESEM, and TEM. Thermo-mechanical properties of PUNHs increase with the increase of nanohybrid content in the pristine PU. Chemical resistance and UV-aging capabilities of PUNHs increase, whereas biodegradation of them decreases with the increase of nanohybrid concentration in the pristine PU. The catalytic activities as well as anticorrosive performance of the nanocomposite were found to be excellent. PUNH1.5 showed proficient catalytic efficiency for the synthesis of N-(4-nitrobenzylidene)aniline with high yield (∼ 83 %). The used nanocomposite was recycled for five times without significant loss of activity. Furthermore, PUNH1.5 showed favorable corrosion current density (9.64 × 10-9A/cm2), corrosion potential (-0.318 V) and corrosion rate of 5.98 × 10-4 mm/yr after 8 days of exposure in 3.5 weight percentage NaCl aqueous solution." @default.
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- W3032962016 date "2020-10-01" @default.
- W3032962016 modified "2023-09-24" @default.
- W3032962016 title "Bio-derived water dispersible polyurethane/rGO@α-MnO2/rGO@δ-MnO2 nanocomposite as a heterogeneous catalyst and anticorrosive material" @default.
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- W3032962016 doi "https://doi.org/10.1016/j.colsurfa.2020.125116" @default.
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