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• W3033120995 abstract "To gain more insight into the factors controlling efficient cysteine arylation by cyclometallated AuIII complexes, the reaction between selected gold compounds and different peptides was investigated by high-resolution liquid chromatography electrospray ionization mass spectrometry (HR-LC-ESI-MS). The deduced mechanisms of C−S cross-coupling, also supported by density functional theory (DFT) and quantum mechanics/molecular mechanics (QM/MM) calculations, evidenced the key role of secondary peptidic gold binding sites in favouring the process of reductive elimination." @default.
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• W3033120995 date "2020-07-08" @default.
• W3033120995 modified "2023-09-27" @default.
• W3033120995 title "Exploring the Chemoselectivity towards Cysteine Arylation by Cyclometallated Au ^III Compounds: New Mechanistic Insights" @default.
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• W3033120995 doi "https://doi.org/10.1002/cbic.202000262" @default.
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