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- W3033131844 abstract "We report herein an efficient aluminum-catalyzed asymmetric MPV reduction of ketones with broad substrate scope and excellent yields and enantiomeric inductions. A variety of aromatic (both electron-poor and electron-rich) and aliphatic ketones were converted to chiral alcohols in good yields with high enantioselectivities (26 examples, 70–98% yield and 82–99% ee). This method operates under mild conditions (−10 °C) and low catalyst loading (1–5 mol %). Furthermore, this process is catalyzed by the earth-abundant main-group element aluminum and employs 2-propanol as the hydride source." @default.
- W3033131844 created "2020-06-12" @default.
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- W3033131844 date "2020-06-01" @default.
- W3033131844 modified "2023-10-13" @default.
- W3033131844 title "Asymmetric Catalytic Meerwein–Ponndorf–Verley Reduction of Ketones with Aluminum(III)-VANOL Catalysts" @default.
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- W3033131844 doi "https://doi.org/10.1021/acscatal.0c01734" @default.
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