Matches in SemOpenAlex for { <https://semopenalex.org/work/W3033237479> ?p ?o ?g. }
- W3033237479 endingPage "8246" @default.
- W3033237479 startingPage "8238" @default.
- W3033237479 abstract "The lanthanide complexes EuL3, GdL3, YbL3 and LuL3 of the N,N'-bis(2-hydroxy-di-3,5-tert-butylphenyl)amine were prepared. The X-Ray crystal structures of GdL3 and LuL3 demonstrated a nine-coordinate sphere with three ligand molecules under their anionic diamagnetic form (Cat-N-BQ)-. The complexes showed three oxidation events (Eox11/2 = 0.15-0.16 V, E1/22 = 0.51-55 V, and E1/23 = 0.75-0.78 V vs. Fc+/Fc) via cyclic voltammetry, corresponding to the successive oxidation of the aminophenolate moeities to iminosemiquinone species. The complexes GdL3 and YbL3 were characterized by EPR spectroscopy, allowing for the determination of the zero field splitting (ZFS) parameters in the first case. The monocations (LnL3)+ and monoanions (LnL3)- were electrochemically generated (Ln = Eu, Gd, Yb, Lu), as well as the dications YbL32+ and LuL32+. The spins are antiferromagnetically exchange coupled in the diradical species LuL32+ (|D| = 260 MHz, E = 0). All the complexes (incl. neutral) possess a strong absorption band in the NIR region (730-840 nm, ε > 19 mM-1 cm-1) corresponding to ligand-based transitions." @default.
- W3033237479 created "2020-06-12" @default.
- W3033237479 creator A5002190866 @default.
- W3033237479 creator A5011049542 @default.
- W3033237479 creator A5027477133 @default.
- W3033237479 creator A5033192994 @default.
- W3033237479 creator A5057626728 @default.
- W3033237479 creator A5060463474 @default.
- W3033237479 creator A5070479979 @default.
- W3033237479 creator A5084323577 @default.
- W3033237479 creator A5088137889 @default.
- W3033237479 date "2020-01-01" @default.
- W3033237479 modified "2023-10-15" @default.
- W3033237479 title "Structural and spectroscopic investigations of nine-coordinate redox active lanthanide complexes with a pincer O,N,O ligand" @default.
- W3033237479 cites W1968400590 @default.
- W3033237479 cites W1968830850 @default.
- W3033237479 cites W1969726382 @default.
- W3033237479 cites W1969848541 @default.
- W3033237479 cites W1970225878 @default.
- W3033237479 cites W1971395362 @default.
- W3033237479 cites W1976554208 @default.
- W3033237479 cites W1977178342 @default.
- W3033237479 cites W1978068772 @default.
- W3033237479 cites W1983098087 @default.
- W3033237479 cites W1989524551 @default.
- W3033237479 cites W1995609027 @default.
- W3033237479 cites W1998092231 @default.
- W3033237479 cites W2011384253 @default.
- W3033237479 cites W2015834387 @default.
- W3033237479 cites W2016336219 @default.
- W3033237479 cites W2019659445 @default.
- W3033237479 cites W2020257119 @default.
- W3033237479 cites W2027488304 @default.
- W3033237479 cites W2028623083 @default.
- W3033237479 cites W2028832730 @default.
- W3033237479 cites W2029188834 @default.
- W3033237479 cites W2033158026 @default.
- W3033237479 cites W2042838493 @default.
- W3033237479 cites W2045894490 @default.
- W3033237479 cites W2049147267 @default.
- W3033237479 cites W2049466083 @default.
- W3033237479 cites W2049965641 @default.
- W3033237479 cites W2052830765 @default.
- W3033237479 cites W2053818670 @default.
- W3033237479 cites W2056422744 @default.
- W3033237479 cites W2058765331 @default.
- W3033237479 cites W2059205366 @default.
- W3033237479 cites W2059599562 @default.
- W3033237479 cites W2070762852 @default.
- W3033237479 cites W2072285153 @default.
- W3033237479 cites W2076503435 @default.
- W3033237479 cites W2084022836 @default.
- W3033237479 cites W2088149855 @default.
- W3033237479 cites W2103029770 @default.
- W3033237479 cites W2107055594 @default.
- W3033237479 cites W2107699082 @default.
- W3033237479 cites W2107924843 @default.
- W3033237479 cites W2112182596 @default.
- W3033237479 cites W2117867509 @default.
- W3033237479 cites W2143252223 @default.
- W3033237479 cites W2150969454 @default.
- W3033237479 cites W2163572838 @default.
- W3033237479 cites W2171892019 @default.
- W3033237479 cites W2266544348 @default.
- W3033237479 cites W2271578821 @default.
- W3033237479 cites W2292812353 @default.
- W3033237479 cites W2319678205 @default.
- W3033237479 cites W2319680161 @default.
- W3033237479 cites W2324824991 @default.
- W3033237479 cites W2325293649 @default.
- W3033237479 cites W2332928565 @default.
- W3033237479 cites W2333708557 @default.
- W3033237479 cites W2337549767 @default.
- W3033237479 cites W2511904551 @default.
- W3033237479 cites W2559302025 @default.
- W3033237479 cites W2560081603 @default.
- W3033237479 cites W2739704026 @default.
- W3033237479 cites W2744331547 @default.
- W3033237479 cites W2796242688 @default.
- W3033237479 cites W2808808196 @default.
- W3033237479 cites W2889290599 @default.
- W3033237479 cites W2973012771 @default.
- W3033237479 cites W633280518 @default.
- W3033237479 doi "https://doi.org/10.1039/d0dt01388a" @default.
- W3033237479 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32510087" @default.
- W3033237479 hasPublicationYear "2020" @default.
- W3033237479 type Work @default.
- W3033237479 sameAs 3033237479 @default.
- W3033237479 citedByCount "7" @default.
- W3033237479 countsByYear W30332374792020 @default.
- W3033237479 countsByYear W30332374792021 @default.
- W3033237479 countsByYear W30332374792023 @default.
- W3033237479 crossrefType "journal-article" @default.
- W3033237479 hasAuthorship W3033237479A5002190866 @default.
- W3033237479 hasAuthorship W3033237479A5011049542 @default.
- W3033237479 hasAuthorship W3033237479A5027477133 @default.
- W3033237479 hasAuthorship W3033237479A5033192994 @default.
- W3033237479 hasAuthorship W3033237479A5057626728 @default.