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- W3033315575 abstract "A series of alkali metal hydroxides (MeOH, Me = Li, Na, K and Cs) were used as the precipitant to prepare the Pd/H-ZSM-5-Me catalysts by deposition-precipitation; the effect of alkali metal cations on the catalytic performance of Pd/H-ZSM-5 in the combustion of lean methane was then investigated. The results indicate that in comparison with ammonia, alkali metal hydroxides as the precipitant can greatly enhance the catalytic performance of Pd/H-ZSM-5 in lean methane combustion and the extent of promoting effect follows the order of CsOH > KOH > NaOH > LiOH >> NH4OH. The alkali metal cations can enhance the dispersion of Pd on the H-ZSM-5 support and effectively reduce the size of Pd particles; in addition, the alkali metal cations may serve as an electron-donating component and endow the Pd species with a unique electronic characteristic, which can promote the activation of C–H bond of methane molecules." @default.
- W3033315575 created "2020-06-12" @default.
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- W3033315575 date "2020-07-01" @default.
- W3033315575 modified "2023-10-16" @default.
- W3033315575 title "Promoting effect of alkali metal cations on the catalytic performance of Pd/H-ZSM-5 in the combustion of lean methane" @default.
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- W3033315575 doi "https://doi.org/10.1016/j.apcata.2020.117678" @default.
- W3033315575 hasPublicationYear "2020" @default.
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