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- W3033429401 abstract "Abstract A major problem concerning the mechanical properties of calcium phosphate cements (CPC) is related to their inherent brittleness, which limits their applicability to non-load bearing bone defects. In this work the preparation of a damage tolerant CPC is presented, where the incorporation of functionalized carbon fibers facilitates steady state flat crack propagation with crack openings below 10 µm. A subsequent self-healing process in simulated body fluid, that mimics the in vivo mineralization of bioactive surfaces, closes the cracks and completely restores the mechanical properties. Hereby, two pathways of self-healing are presented: i) intrinsic healing that bases on the inherent bioactive properties of the cement matrix and chemically treated fibers, and ii) capsule based extrinsic healing, where H 2 PO 4 - is released as an initiator for the apatite formation. Such damage tolerant CPCs with self-healing capacity are of particular interest to increase the lifetime of implants as well as in the field of load-bearing bioceramics." @default.
- W3033429401 created "2020-06-12" @default.
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- W3033429401 date "2020-06-10" @default.
- W3033429401 modified "2023-09-23" @default.
- W3033429401 title "Self-healing capacity of fiber-reinforced calcium phosphate cements" @default.
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- W3033429401 doi "https://doi.org/10.1038/s41598-020-66207-2" @default.
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