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- W3033450079 abstract "A series of technetium complexes with the sterically encumbered m-terphenyl isocyanides CNArDipp2 (Dipp = 2,6-diisopropylphenyl) and CNArMes2 (Mes = 2,4,6-trimethylphenyl) has been prepared. The products span three different oxidation states (+1, +3, and +5) of the radioactive transition metal and comprise carbonyl, nitrosyl, chloride, and nitrido complexes. All members of this series (trans,mer-[TcI(CO)3Cl(CNArDipp2)], trans-[TcI(NO)Cl2(PPh3)(CNArDipp2)2], [TcIIICl3(PMe2Ph)2(L)] (L = CNArDipp2, CNArMes2), trans-[TcVNCl2(CNArDipp2)2], cis-[TcVNCl2(CNArMes2)2(L)] (L = H2O, MeOH), cis-[TcVNBr2(CNArMes2)2], and trans-[TcV(NPh)X2(CNArDipp2)2] (X = Cl, Br)) are stable under ambient conditions. The νCN IR frequencies measured for the complexes frequently appear at wavenumbers higher than those for the uncoordinated isocyanides, which suggests a low degree of back-donation into the CN π* orbitals of these ligands." @default.
- W3033450079 created "2020-06-12" @default.
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- W3033450079 date "2020-06-03" @default.
- W3033450079 modified "2023-10-09" @default.
- W3033450079 title "Structural and Redox Variations in Technetium Complexes Supported by <i>m</i>-Terphenyl Isocyanides" @default.
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- W3033450079 doi "https://doi.org/10.1021/acs.organomet.0c00238" @default.
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