FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3033475795> ?p ?o ?g. }

• W3033475795 abstract "Abstract The biopolyester cutin is ubiquitous in land plants, building the polymeric matrix of the plant’s outermost defensive barrier - the cuticle. Cutin influences many biological processes in planta however due to its complexity and highly branched nature, the native structure remains partially unresolved. Our aim was to define an original workflow for the purification and systematic characterisation of the molecular structure of cutin. To purify cutin we tested the ionic liquids cholinium hexanoate and 1-butyl-3-methyl-imidazolium acetate. The ensuing polymers are highly esterified, amorphous and have the typical monomeric composition as demonstrated by solid state NMR, complemented by spectroscopic (GC-MS), thermal (DSC) and x-ray scattering (WAXS) analyses. A systematic study by solution-state NMR of cryogenically milled cutins extracted from Micro-Tom tomatoes (the wild type and the gpat6 and cus1 mutants) was undertaken. Their molecular structures, relative distribution of ester aliphatics, free acid end-groups and free hydroxyl groups, differentiating between those derived from primary and secondary esters, were solved. The acquired data demonstrate the existence of free hydroxyl groups in cutin and reveal novel insights on how the mutations impact the esterification arrangement of cutin. Compared to conventional approaches, the usage of ionic liquids for the study of plant polyesters opens new avenues since simple modifications can be applied to recover a biopolymer carrying distinct types/degrees of modifications ( e.g . preservation of esters or cuticular polysaccharides), which in combination with the solution NMR methodologies developed here, constitutes now essential tools to fingerprint the multi-functionality and the structure of cutin in planta ." @default.
• W3033475795 created "2020-06-12" @default.
• W3033475795 creator A5007472847 @default.
• W3033475795 creator A5007998185 @default.
• W3033475795 creator A5013038487 @default.
• W3033475795 creator A5015072386 @default.
• W3033475795 creator A5019525132 @default.
• W3033475795 creator A5055126899 @default.
• W3033475795 creator A5062652088 @default.
• W3033475795 creator A5076470338 @default.
• W3033475795 creator A5078431293 @default.
• W3033475795 creator A5080716262 @default.
• W3033475795 creator A5090712504 @default.
• W3033475795 date "2020-06-02" @default.
• W3033475795 modified "2023-09-27" @default.
• W3033475795 title "Novel ionic liquids-based extraction method that preserves molecular structure from cutin" @default.
• W3033475795 cites W1600292521 @default.
• W3033475795 cites W1626833108 @default.
• W3033475795 cites W1804081258 @default.
• W3033475795 cites W1977004545 @default.
• W3033475795 cites W1986752839 @default.
• W3033475795 cites W1989529205 @default.
• W3033475795 cites W1999321996 @default.
• W3033475795 cites W2003942577 @default.
• W3033475795 cites W2016213308 @default.
• W3033475795 cites W2035357021 @default.
• W3033475795 cites W2036573647 @default.
• W3033475795 cites W2037453527 @default.
• W3033475795 cites W2048370674 @default.
• W3033475795 cites W2064370050 @default.
• W3033475795 cites W2085359348 @default.
• W3033475795 cites W2095554773 @default.
• W3033475795 cites W2107954823 @default.
• W3033475795 cites W2120601344 @default.
• W3033475795 cites W2139542543 @default.
• W3033475795 cites W2140721446 @default.
• W3033475795 cites W2141061210 @default.
• W3033475795 cites W2154144130 @default.
• W3033475795 cites W2158460435 @default.
• W3033475795 cites W2208285559 @default.
• W3033475795 cites W2283959282 @default.
• W3033475795 cites W2337399094 @default.
• W3033475795 cites W2338164714 @default.
• W3033475795 cites W2439019935 @default.
• W3033475795 cites W2467445214 @default.
• W3033475795 cites W2529123142 @default.
• W3033475795 cites W2547119088 @default.
• W3033475795 cites W2564596535 @default.
• W3033475795 cites W2743808310 @default.
• W3033475795 cites W2753859241 @default.
• W3033475795 cites W2754401295 @default.
• W3033475795 cites W2768420817 @default.
• W3033475795 cites W2787064452 @default.
• W3033475795 cites W2794119484 @default.
• W3033475795 cites W2897556373 @default.
• W3033475795 cites W2899670569 @default.
• W3033475795 cites W2920709194 @default.
• W3033475795 cites W2997526885 @default.
• W3033475795 doi "https://doi.org/10.1101/2020.06.01.127837" @default.
• W3033475795 hasPublicationYear "2020" @default.
• W3033475795 type Work @default.
• W3033475795 sameAs 3033475795 @default.
• W3033475795 citedByCount "0" @default.
• W3033475795 crossrefType "posted-content" @default.
• W3033475795 hasAuthorship W3033475795A5007472847 @default.
• W3033475795 hasAuthorship W3033475795A5007998185 @default.
• W3033475795 hasAuthorship W3033475795A5013038487 @default.
• W3033475795 hasAuthorship W3033475795A5015072386 @default.
• W3033475795 hasAuthorship W3033475795A5019525132 @default.
• W3033475795 hasAuthorship W3033475795A5055126899 @default.
• W3033475795 hasAuthorship W3033475795A5062652088 @default.
• W3033475795 hasAuthorship W3033475795A5076470338 @default.
• W3033475795 hasAuthorship W3033475795A5078431293 @default.
• W3033475795 hasAuthorship W3033475795A5080716262 @default.
• W3033475795 hasAuthorship W3033475795A5090712504 @default.
• W3033475795 hasBestOaLocation W30334757951 @default.
• W3033475795 hasConcept C119394753 @default.
• W3033475795 hasConcept C127413603 @default.
• W3033475795 hasConcept C153033020 @default.
• W3033475795 hasConcept C178790620 @default.
• W3033475795 hasConcept C185592680 @default.
• W3033475795 hasConcept C24361215 @default.
• W3033475795 hasConcept C2776915729 @default.
• W3033475795 hasConcept C2778636629 @default.
• W3033475795 hasConcept C42360764 @default.
• W3033475795 hasConcept C521977710 @default.
• W3033475795 hasConcept C55493867 @default.
• W3033475795 hasConceptScore W3033475795C119394753 @default.
• W3033475795 hasConceptScore W3033475795C127413603 @default.
• W3033475795 hasConceptScore W3033475795C153033020 @default.
• W3033475795 hasConceptScore W3033475795C178790620 @default.
• W3033475795 hasConceptScore W3033475795C185592680 @default.
• W3033475795 hasConceptScore W3033475795C24361215 @default.
• W3033475795 hasConceptScore W3033475795C2776915729 @default.
• W3033475795 hasConceptScore W3033475795C2778636629 @default.
• W3033475795 hasConceptScore W3033475795C42360764 @default.
• W3033475795 hasConceptScore W3033475795C521977710 @default.
• W3033475795 hasConceptScore W3033475795C55493867 @default.
• W3033475795 hasLocation W30334757951 @default.
• W3033475795 hasLocation W30334757952 @default.

• next