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- W3033482591 endingPage "125793" @default.
- W3033482591 startingPage "125793" @default.
- W3033482591 abstract "Applying direct bio-oil derived from lignocellulosic materials via thermochemical processes i.e. pyrolysis to internal combustion engines is challenging due to its high oxygen content (30–40%) and thermal and chemical instability. Despite numerous efforts, the hydrodeoxygenation processes have encountered a number of issues such as rapid catalyst deactivation, large amount of hydrogen required (600–1000 L hydrogen per kilogram of bio-oil), high pressure (up to 300 bar), high temperatures (250–450 °C) and long reaction time (3–4 h). In this study, cold plasma operated at atmospheric conditions was applied for hydrodeoxygenation of guaiacol, a model compound to understand the mechanism, effect of operating conditions and interactions between catalyst and cold plasma on oxygen removal. Approximately 82% of guaiacol was converted into catechol, phenol, benzene and toluene within 3–4 s without catalysts. Adding the catalyst of cobalt supported on silica dioxide in the plasma zone enhanced the production of phenol to 44% at H2 requirement of 315 L.kg−1 of guaiacol." @default.
- W3033482591 created "2020-06-12" @default.
- W3033482591 creator A5065474346 @default.
- W3033482591 creator A5084357142 @default.
- W3033482591 date "2020-12-01" @default.
- W3033482591 modified "2023-10-17" @default.
- W3033482591 title "Intensification of hydrodeoxygenation of liquid derived from pyrolysis: Guaiacol as model compound" @default.
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- W3033482591 doi "https://doi.org/10.1016/j.cej.2020.125793" @default.
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