Matches in SemOpenAlex for { <https://semopenalex.org/work/W3033508755> ?p ?o ?g. }
- W3033508755 endingPage "9626" @default.
- W3033508755 startingPage "9618" @default.
- W3033508755 abstract "The characteristic red color of many natural tourmalines is due to the presence of Mn(III) cations substituting for aluminum and lithium. These sites originate as Mn(II) and are oxidized by natural γ-irradiation over geologic time as they sit in the Earth’s crust. Presented here is a thorough analysis of the spin-allowed and spin-forbidden transitions which give rise to the color of these gemstones. Ligand field analysis, supplemented by time-dependent density functional theory, was used to correct the historical assignments of the symmetry-allowed transitions in the polarized UV–visible absorption spectrum. Heat-induced reduction of the oxidized manganese sites provided a probe of the relationship between the spin-allowed and spin-forbidden bands. Notably, the intensity of the spin-forbidden transition was highly dependent on the neighboring ions in the Y-site. Simulations and modeling showed that increased intensity was observed only when two Mn(III) ions occupied adjacent substitutions in the Y-site via a proposed exchange-coupling mechanism." @default.
- W3033508755 created "2020-06-12" @default.
- W3033508755 creator A5002489307 @default.
- W3033508755 creator A5009206599 @default.
- W3033508755 creator A5052428851 @default.
- W3033508755 date "2020-06-05" @default.
- W3033508755 modified "2023-09-24" @default.
- W3033508755 title "The Nature of the Mn(III) Color Centers in Elbaite Tourmalines" @default.
- W3033508755 cites W1489797013 @default.
- W3033508755 cites W1793734046 @default.
- W3033508755 cites W1970212419 @default.
- W3033508755 cites W1996881597 @default.
- W3033508755 cites W2030303793 @default.
- W3033508755 cites W2031348208 @default.
- W3033508755 cites W2035126464 @default.
- W3033508755 cites W2036896790 @default.
- W3033508755 cites W2046193942 @default.
- W3033508755 cites W2049318563 @default.
- W3033508755 cites W2057458343 @default.
- W3033508755 cites W2063498452 @default.
- W3033508755 cites W2064691256 @default.
- W3033508755 cites W2065454111 @default.
- W3033508755 cites W2067718414 @default.
- W3033508755 cites W2070761458 @default.
- W3033508755 cites W2078146328 @default.
- W3033508755 cites W2093451739 @default.
- W3033508755 cites W2093700672 @default.
- W3033508755 cites W2095291329 @default.
- W3033508755 cites W2108987047 @default.
- W3033508755 cites W2127251078 @default.
- W3033508755 cites W2270883213 @default.
- W3033508755 cites W2318914198 @default.
- W3033508755 cites W2333768320 @default.
- W3033508755 cites W2334937148 @default.
- W3033508755 cites W2341404763 @default.
- W3033508755 cites W2479555842 @default.
- W3033508755 cites W4247537791 @default.
- W3033508755 doi "https://doi.org/10.1021/acs.inorgchem.0c00722" @default.
- W3033508755 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32501711" @default.
- W3033508755 hasPublicationYear "2020" @default.
- W3033508755 type Work @default.
- W3033508755 sameAs 3033508755 @default.
- W3033508755 citedByCount "2" @default.
- W3033508755 countsByYear W30335087552022 @default.
- W3033508755 crossrefType "journal-article" @default.
- W3033508755 hasAuthorship W3033508755A5002489307 @default.
- W3033508755 hasAuthorship W3033508755A5009206599 @default.
- W3033508755 hasAuthorship W3033508755A5052428851 @default.
- W3033508755 hasConcept C121332964 @default.
- W3033508755 hasConcept C125287762 @default.
- W3033508755 hasConcept C127413603 @default.
- W3033508755 hasConcept C134018914 @default.
- W3033508755 hasConcept C145148216 @default.
- W3033508755 hasConcept C146978453 @default.
- W3033508755 hasConcept C178790620 @default.
- W3033508755 hasConcept C185592680 @default.
- W3033508755 hasConcept C24890656 @default.
- W3033508755 hasConcept C2778541603 @default.
- W3033508755 hasConcept C42704618 @default.
- W3033508755 hasConcept C528890316 @default.
- W3033508755 hasConcept C57805442 @default.
- W3033508755 hasConcept C71924100 @default.
- W3033508755 hasConcept C75473681 @default.
- W3033508755 hasConcept C8010536 @default.
- W3033508755 hasConceptScore W3033508755C121332964 @default.
- W3033508755 hasConceptScore W3033508755C125287762 @default.
- W3033508755 hasConceptScore W3033508755C127413603 @default.
- W3033508755 hasConceptScore W3033508755C134018914 @default.
- W3033508755 hasConceptScore W3033508755C145148216 @default.
- W3033508755 hasConceptScore W3033508755C146978453 @default.
- W3033508755 hasConceptScore W3033508755C178790620 @default.
- W3033508755 hasConceptScore W3033508755C185592680 @default.
- W3033508755 hasConceptScore W3033508755C24890656 @default.
- W3033508755 hasConceptScore W3033508755C2778541603 @default.
- W3033508755 hasConceptScore W3033508755C42704618 @default.
- W3033508755 hasConceptScore W3033508755C528890316 @default.
- W3033508755 hasConceptScore W3033508755C57805442 @default.
- W3033508755 hasConceptScore W3033508755C71924100 @default.
- W3033508755 hasConceptScore W3033508755C75473681 @default.
- W3033508755 hasConceptScore W3033508755C8010536 @default.
- W3033508755 hasFunder F4320332916 @default.
- W3033508755 hasIssue "14" @default.
- W3033508755 hasLocation W30335087551 @default.
- W3033508755 hasLocation W30335087552 @default.
- W3033508755 hasOpenAccess W3033508755 @default.
- W3033508755 hasPrimaryLocation W30335087551 @default.
- W3033508755 hasRelatedWork W2026343010 @default.
- W3033508755 hasRelatedWork W2069219306 @default.
- W3033508755 hasRelatedWork W2109247508 @default.
- W3033508755 hasRelatedWork W2344360015 @default.
- W3033508755 hasRelatedWork W2950449520 @default.
- W3033508755 hasRelatedWork W2950700875 @default.
- W3033508755 hasRelatedWork W2951930221 @default.
- W3033508755 hasRelatedWork W2952131698 @default.
- W3033508755 hasRelatedWork W2953182515 @default.
- W3033508755 hasRelatedWork W3135978960 @default.
- W3033508755 hasVolume "59" @default.
- W3033508755 isParatext "false" @default.