Matches in SemOpenAlex for { <https://semopenalex.org/work/W3033590959> ?p ?o ?g. }
- W3033590959 endingPage "109831" @default.
- W3033590959 startingPage "109831" @default.
- W3033590959 abstract "Block copolymers (BCPs) with a high Flory–Huggins interaction parameter (χ) are promising alternatives to conventional nanopatterning materials for future nanolithography and nanotechnology applications. Herein, we described AB- and ABA-type BCPs comprising oligosaccharides (maltoheptaose, maltotriose, and maltose as the A block) and poly(propylene oxide) (PPO, as the B block) as new high-χ BCP systems, which can be termed “Sweet Pluronics”. The BCPs were successfully synthesized by click reaction between azido-functionalized PPO and propargyl-functionalized maltooligosaccharides. These BCPs undergo microphase separation in bulk state to provide various nanopatterns, i.e., sub-4 nm nanofeatures (cylinders, lamellae, and spheres) with domain spacing as low as 6.2 nm, depending on their composition and the applied annealing conditions. The thin film of these BCPs fabricated on a silicon substrate also showed various microphase-separated structures. When the BCP thin films were subjected to high-temperature solvent vapor annealing using a µ-wave oven as the heating source, their morphologies changed from parallel lamellar to cylindrical because of the preferential swelling of PPO. Overall, these results confirmed that the present “Sweet Pluronics” system is promising high-χ materials for sub-4 nm nanopatterning applications." @default.
- W3033590959 created "2020-06-12" @default.
- W3033590959 creator A5000805609 @default.
- W3033590959 creator A5023065306 @default.
- W3033590959 creator A5023880535 @default.
- W3033590959 creator A5025111931 @default.
- W3033590959 creator A5047493834 @default.
- W3033590959 creator A5054515788 @default.
- W3033590959 creator A5061834004 @default.
- W3033590959 creator A5073210331 @default.
- W3033590959 date "2020-07-01" @default.
- W3033590959 modified "2023-09-23" @default.
- W3033590959 title "Sweet Pluronic poly(propylene oxide)-b-oligosaccharide block copolymer systems: Toward sub-4 nm thin-film nanopattern resolution" @default.
- W3033590959 cites W1852362221 @default.
- W3033590959 cites W1966824797 @default.
- W3033590959 cites W1969817290 @default.
- W3033590959 cites W1969937980 @default.
- W3033590959 cites W1974374350 @default.
- W3033590959 cites W1982271883 @default.
- W3033590959 cites W1982690373 @default.
- W3033590959 cites W1999388206 @default.
- W3033590959 cites W2003398981 @default.
- W3033590959 cites W2009188082 @default.
- W3033590959 cites W2010675452 @default.
- W3033590959 cites W2011963980 @default.
- W3033590959 cites W2020337437 @default.
- W3033590959 cites W2034501059 @default.
- W3033590959 cites W2036948901 @default.
- W3033590959 cites W2039783058 @default.
- W3033590959 cites W2042910965 @default.
- W3033590959 cites W2044717280 @default.
- W3033590959 cites W2046875460 @default.
- W3033590959 cites W2058827055 @default.
- W3033590959 cites W2061798607 @default.
- W3033590959 cites W2073245411 @default.
- W3033590959 cites W2074900313 @default.
- W3033590959 cites W2085554061 @default.
- W3033590959 cites W2086892631 @default.
- W3033590959 cites W2092646296 @default.
- W3033590959 cites W2093640652 @default.
- W3033590959 cites W2094208954 @default.
- W3033590959 cites W2094443469 @default.
- W3033590959 cites W2098372094 @default.
- W3033590959 cites W2104212315 @default.
- W3033590959 cites W2111072645 @default.
- W3033590959 cites W2171775863 @default.
- W3033590959 cites W2172949807 @default.
- W3033590959 cites W2283269778 @default.
- W3033590959 cites W2323699776 @default.
- W3033590959 cites W2325688691 @default.
- W3033590959 cites W2395666553 @default.
- W3033590959 cites W2478199472 @default.
- W3033590959 cites W2518375234 @default.
- W3033590959 cites W2555020681 @default.
- W3033590959 cites W2604477058 @default.
- W3033590959 cites W2727997567 @default.
- W3033590959 cites W2735490381 @default.
- W3033590959 cites W2781846857 @default.
- W3033590959 cites W2885872865 @default.
- W3033590959 cites W2888441702 @default.
- W3033590959 cites W2889954002 @default.
- W3033590959 cites W2894995332 @default.
- W3033590959 cites W2910730543 @default.
- W3033590959 cites W2952267589 @default.
- W3033590959 cites W2975639389 @default.
- W3033590959 cites W2989466031 @default.
- W3033590959 cites W4233417203 @default.
- W3033590959 doi "https://doi.org/10.1016/j.eurpolymj.2020.109831" @default.
- W3033590959 hasPublicationYear "2020" @default.
- W3033590959 type Work @default.
- W3033590959 sameAs 3033590959 @default.
- W3033590959 citedByCount "8" @default.
- W3033590959 countsByYear W30335909592020 @default.
- W3033590959 countsByYear W30335909592021 @default.
- W3033590959 countsByYear W30335909592022 @default.
- W3033590959 countsByYear W30335909592023 @default.
- W3033590959 crossrefType "journal-article" @default.
- W3033590959 hasAuthorship W3033590959A5000805609 @default.
- W3033590959 hasAuthorship W3033590959A5023065306 @default.
- W3033590959 hasAuthorship W3033590959A5023880535 @default.
- W3033590959 hasAuthorship W3033590959A5025111931 @default.
- W3033590959 hasAuthorship W3033590959A5047493834 @default.
- W3033590959 hasAuthorship W3033590959A5054515788 @default.
- W3033590959 hasAuthorship W3033590959A5061834004 @default.
- W3033590959 hasAuthorship W3033590959A5073210331 @default.
- W3033590959 hasBestOaLocation W30335909592 @default.
- W3033590959 hasConcept C127413603 @default.
- W3033590959 hasConcept C15920480 @default.
- W3033590959 hasConcept C159985019 @default.
- W3033590959 hasConcept C171250308 @default.
- W3033590959 hasConcept C188027245 @default.
- W3033590959 hasConcept C19067145 @default.
- W3033590959 hasConcept C192562407 @default.
- W3033590959 hasConcept C2777505466 @default.
- W3033590959 hasConcept C2777801237 @default.
- W3033590959 hasConcept C2777855556 @default.
- W3033590959 hasConcept C42360764 @default.
- W3033590959 hasConcept C521977710 @default.