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• W3033607572 endingPage "146800" @default.
• W3033607572 startingPage "146800" @default.
• W3033607572 abstract "Abstract Cu2NiGeS4 (CNGS) thin film has been obtained for the first time. The synthesis was done via spray ultrasonic deposition of Cu − Ni − Ge precursors (aqueous salt) onto glass substrate (Ts = 180 °C), followed by high-temperature sulfurization under inert atmosphere (500 °C − Ar − S8). X − Ray − Diffraction (XRD) and Raman spectroscopy analysis confirm the formation of polycrystalline Cu2NiGeS4 (CNGS) with tetragonal kesterite ( I 4 - ) structure. A near stoichiometry 2:1:1:4 of Cu − Ni − Ge − S was confirmed by Energy Dispersive X − ray Analysis (EDX). The Hall Effect measurement reveals the p − type semiconductor of Cu2NiGeS4 thin film. The theoretical calculation based on the density functional theory (DFT) shows a direct band gap (band structure). The experimental and theoretical optical band gap found to be in the range of 1.60–1.8 eV with high absorption coefficient ( > 10 4 c m - 1 ) in the visible spectra. The obtained results will be a basis to develop these materials in the field of photovoltaics." @default.
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• W3033607572 date "2020-10-01" @default.
• W3033607572 modified "2023-09-25" @default.
• W3033607572 title "Experimental and theoretical study of new kesterite Cu2NiGeS4 thin film synthesized via spray ultrasonic technic" @default.
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• W3033607572 doi "https://doi.org/10.1016/j.apsusc.2020.146800" @default.
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