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- W3033620250 abstract "Hydrofluoroolefins (HFOs) and cyclic hydrofluorocarbons (c-HFCs) have been the most favored alternatives of the ozone depletion substances; however, because of the poor performance of the present chlorine/fluorine (Cl/F) exchange catalysts, the development and production of HFOs and c-HFCs are hindered. Here, we first report a novel and facile route to fabricate high-performance Cl/F exchange catalysts via a metal-organic framework (MOF) carbonization method. The MOF-derived catalyst not only has high selectivity but also can significantly lower the reaction temperature. Moreover, benefiting from the stable structure and coke-inhibiting ability, the MOF-derived catalyst has a long service life compared with the traditional precipitation method. Furthermore, the nanoscopic MOF-derived catalyst can greatly reduce the Cr dosage, which would help to minimize the risk of Cr contamination." @default.
- W3033620250 created "2020-06-12" @default.
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- W3033620250 date "2020-06-01" @default.
- W3033620250 modified "2023-10-14" @default.
- W3033620250 title "Metal–Organic Framework-Derived Strategy for Improving Catalytic Performance of a Chromia-Based Catalyst in the Chlorine/Fluorine Exchange Reactions for Unsaturated Fluorocarbons" @default.
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- W3033620250 doi "https://doi.org/10.1021/acsomega.0c01128" @default.
- W3033620250 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7288590" @default.
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