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• W3033675082 abstract "Structural and magnetic properties of cubic spinel selenides $mathrm{Ga}{M}_{4}{mathrm{Se}}_{8}$ ($M=mathrm{Nb}$, Ta), which are candidates for the molecular ${J}_{mathrm{eff}}=3/2$ Mott insulators, are investigated. The effective magnetic moments are reduced compared to the spin only value, indicating the presence of sizable spin-orbit coupling. ${mathrm{GaNb}}_{4}{mathrm{Se}}_{8}$ and ${mathrm{GaTa}}_{4}{mathrm{Se}}_{8}$ exhibit phase transitions into the nonmagnetic ground states with orthorhombic and tetragonal structures, respectively, which are robust against magnetic field up to at least 60 T. A cubic-cubic phase transition is observed in ${mathrm{GaNb}}_{4}{mathrm{Se}}_{8}$ preceding the magnetic transition, suggesting the existence of a quadrupolar-ordered phase theoretically predicted in the ${J}_{mathrm{eff}}=3/2$ Mott insulator." @default.
• W3033675082 created "2020-06-12" @default.
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• W3033675082 date "2020-06-04" @default.
• W3033675082 modified "2023-10-02" @default.
• W3033675082 title "Nonmagnetic Ground States and a Possible Quadrupolar Phase in <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>4</mml:mn><mml:mi>d</mml:mi></mml:mrow></mml:math> and <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>5</mml:mn><mml:mi>d</mml:mi></mml:mrow></mml:math> Lacunar Spinel Selenides <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi>Ga</mml:mi><mml:mrow><mml:msub…" @default.
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• W3033675082 doi "https://doi.org/10.1103/physrevlett.124.227202" @default.
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• W3033675082 hasPublicationYear "2020" @default.
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