FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3033852053> ?p ?o ?g. }

• W3033852053 endingPage "114620" @default.
• W3033852053 startingPage "114620" @default.
• W3033852053 abstract "Mononuclear cobalt(III) complexes of 3,5-di-tert-butylcatecholato cobalt complex of the substituted bis(phenol) diamine ligands of H2LNEX (CoLNEX(DTBC) which X: BM, Bu and OB stands for 2-(tert-butyl)-4-methyl, 2,4-di-tert-butyl and 2-(tert-butyl)-4-methoxy phenols, respectively, and DTBC is an abbreviation for 2,4-di-tert-butylcatechol, as models for enzyme-substrate adducts of catechol dioxygenases, have been synthesized and characterized by different techniques. X-ray structure analysis has revealed that cobalt centers were surrounded by two phenolates, two amine nitrogens and two oxygen atoms of catechol ligand. For all three compounds, the magnetic susceptibility increases with decreasing temperature as expected for non-interacting, magnetic moments which confirm the monomeric structure of cobalt complexes and valence tautomerism between Co(II) and Co(III) oxidation state. Crystal structures confirm the nature of Co(II)/Co(III) character consistent with the magnetic experiments. In electronic absorption spectra of two complexes, the position of LMCT bands show the phenolate(π)-to- Co(II) or Co(III) (dπ*) charge transfer. The cyclic voltammetry studies, show the ligand-centered oxidation of phenolate group to phenoxyl radical." @default.
• W3033852053 created "2020-06-12" @default.
• W3033852053 creator A5026888386 @default.
• W3033852053 creator A5039550999 @default.
• W3033852053 creator A5042165141 @default.
• W3033852053 creator A5072259806 @default.
• W3033852053 date "2020-09-01" @default.
• W3033852053 modified "2023-10-17" @default.
• W3033852053 title "Valence tautomerism in catecholato cobalt Bis(phenolate) diamine complexes as models for Enzyme–substrate adducts of catechol dioxygenases" @default.
• W3033852053 cites W1932909417 @default.
• W3033852053 cites W1972887793 @default.
• W3033852053 cites W1975721848 @default.
• W3033852053 cites W1991354940 @default.
• W3033852053 cites W1992015861 @default.
• W3033852053 cites W1999537827 @default.
• W3033852053 cites W2000865549 @default.
• W3033852053 cites W2001465174 @default.
• W3033852053 cites W2002576040 @default.
• W3033852053 cites W2003733974 @default.
• W3033852053 cites W2016150274 @default.
• W3033852053 cites W2022557711 @default.
• W3033852053 cites W2026827063 @default.
• W3033852053 cites W2028645560 @default.
• W3033852053 cites W2031238252 @default.
• W3033852053 cites W2031966332 @default.
• W3033852053 cites W2034459610 @default.
• W3033852053 cites W2039371681 @default.
• W3033852053 cites W2040198431 @default.
• W3033852053 cites W2048498306 @default.
• W3033852053 cites W2049670030 @default.
• W3033852053 cites W2052895859 @default.
• W3033852053 cites W2065817090 @default.
• W3033852053 cites W2066593626 @default.
• W3033852053 cites W2069839483 @default.
• W3033852053 cites W2070365441 @default.
• W3033852053 cites W2073793481 @default.
• W3033852053 cites W2080928309 @default.
• W3033852053 cites W2081649172 @default.
• W3033852053 cites W2084883964 @default.
• W3033852053 cites W2088505060 @default.
• W3033852053 cites W2088626398 @default.
• W3033852053 cites W2090039888 @default.
• W3033852053 cites W2143252223 @default.
• W3033852053 cites W2156493660 @default.
• W3033852053 cites W2163572838 @default.
• W3033852053 cites W2168704149 @default.
• W3033852053 cites W2323842452 @default.
• W3033852053 cites W2336868360 @default.
• W3033852053 cites W2461115542 @default.
• W3033852053 cites W2591788020 @default.
• W3033852053 cites W2603360340 @default.
• W3033852053 cites W2606376349 @default.
• W3033852053 cites W2728505793 @default.
• W3033852053 cites W2753514374 @default.
• W3033852053 cites W2781034511 @default.
• W3033852053 cites W2783876855 @default.
• W3033852053 cites W2891766517 @default.
• W3033852053 cites W2951171938 @default.
• W3033852053 cites W2951500939 @default.
• W3033852053 cites W2952532516 @default.
• W3033852053 cites W2952955862 @default.
• W3033852053 cites W3010757886 @default.
• W3033852053 cites W4376595661 @default.
• W3033852053 doi "https://doi.org/10.1016/j.poly.2020.114620" @default.
• W3033852053 hasPublicationYear "2020" @default.
• W3033852053 type Work @default.
• W3033852053 sameAs 3033852053 @default.
• W3033852053 citedByCount "5" @default.
• W3033852053 countsByYear W30338520532021 @default.
• W3033852053 countsByYear W30338520532023 @default.
• W3033852053 crossrefType "journal-article" @default.
• W3033852053 hasAuthorship W3033852053A5026888386 @default.
• W3033852053 hasAuthorship W3033852053A5039550999 @default.
• W3033852053 hasAuthorship W3033852053A5042165141 @default.
• W3033852053 hasAuthorship W3033852053A5072259806 @default.
• W3033852053 hasConcept C108204754 @default.
• W3033852053 hasConcept C111233374 @default.
• W3033852053 hasConcept C116569031 @default.
• W3033852053 hasConcept C155647269 @default.
• W3033852053 hasConcept C166940927 @default.
• W3033852053 hasConcept C168900304 @default.
• W3033852053 hasConcept C170493617 @default.
• W3033852053 hasConcept C178790620 @default.
• W3033852053 hasConcept C179104552 @default.
• W3033852053 hasConcept C185592680 @default.
• W3033852053 hasConcept C188027245 @default.
• W3033852053 hasConcept C2777713698 @default.
• W3033852053 hasConcept C2778591166 @default.
• W3033852053 hasConcept C2780871995 @default.
• W3033852053 hasConcept C515602321 @default.
• W3033852053 hasConcept C521977710 @default.
• W3033852053 hasConcept C544153396 @default.
• W3033852053 hasConcept C55493867 @default.
• W3033852053 hasConcept C71240020 @default.
• W3033852053 hasConcept C8010536 @default.
• W3033852053 hasConceptScore W3033852053C108204754 @default.
• W3033852053 hasConceptScore W3033852053C111233374 @default.
• W3033852053 hasConceptScore W3033852053C116569031 @default.

• next