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- W3033856449 endingPage "109832" @default.
- W3033856449 startingPage "109832" @default.
- W3033856449 abstract "As a kind of material possessing thermal stability, biocompatibility and degradability, polysilylethers (PSEs) have potential applications. Different catalytic systems have been developed for the synthesis of PSEs. However, the resulted PSEs have similar structure, which is unfavorable for adjusting its properties. We herein synthesized a series of novel PSEs with pendant SiH groups via cobalt-catalyzed selective dehydrocoupling polymerization. Various diols and prochiral silanes are suitable for this method. This novel PSEs could also be obtained via a Co-catalyzed one-pot two-step process. Furthermore, asymmetric dehydrocoupling polymerization was studied and high-Mn PSE was obtained. After the cleavage of PSE by methyl magnesium iodide, chiral silane was obtained with high yield and moderate enantioselectivity." @default.
- W3033856449 created "2020-06-12" @default.
- W3033856449 creator A5054984389 @default.
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- W3033856449 date "2020-07-01" @default.
- W3033856449 modified "2023-09-27" @default.
- W3033856449 title "Cobalt-catalyzed selective dehydrocoupling polymerization of prochiral silanes and diols" @default.
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- W3033856449 doi "https://doi.org/10.1016/j.eurpolymj.2020.109832" @default.
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