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- W3033870539 endingPage "113508" @default.
- W3033870539 startingPage "113508" @default.
- W3033870539 abstract "Abstract With the aim to explore the effect of heteroatoms on corrosion inhibiting efficacy of structurally similar azomethine based organic molecules, namely, 5-((furan-2-yl)methyleneamino)-2H-1,2,4-triazole-3-thiol (FMT) and 5-((thiophen-2-yl)methyleneamino)-2H-1,2,4-triazole-3-thiol (TMT) were synthesized and its corrosion inhibiting property were investigated by potentiodynamic polarization and non-destructive electrochemical impedance spectroscopy. These electrochemical techniques revealed the excellent corrosion inhibiting efficacy of synthesized inhibitor molecules for mild steel exposed to 1 molL−1 HCl at ambient condition. Surface analyses using FESEM, AFM and contact angle measurement of mild steel retrieved from corrosive medium containing inhibitor molecules confirmed the formation of protective layer of inhibitor molecules on its surface. The consequences of efficient corrosion inhibiting property has been explained based on Hard-Soft-Acid-Base principle as well as electronegativity and polarizability difference of heteroatoms present in the skeleton of inhibitor molecules. Moreover, in order to validate the corrosion inhibiting property obtained from electrochemical experimentations, the insight of corrosion inhibition mechanism has been further explored by employing theoretical calculations viz density functional theory, Fukui indices analyses, molecular dynamics simulation and radial distribution function. Mulliken atomic charges, frontier molecular orbital and Fukui indices analysis of the free as well as adsorbed inhibitor molecules confirms the interaction of the susceptible reactive sites." @default.
- W3033870539 created "2020-06-12" @default.
- W3033870539 creator A5007680672 @default.
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- W3033870539 date "2020-09-01" @default.
- W3033870539 modified "2023-10-02" @default.
- W3033870539 title "Corrosion inhibition property of azomethine functionalized triazole derivatives in 1 mol L−1 HCl medium for mild steel: Experimental and theoretical exploration" @default.
- W3033870539 cites W1916150541 @default.
- W3033870539 cites W1968511284 @default.
- W3033870539 cites W1974479174 @default.
- W3033870539 cites W1976482987 @default.
- W3033870539 cites W1983412855 @default.
- W3033870539 cites W1993806524 @default.
- W3033870539 cites W1994972518 @default.
- W3033870539 cites W1997279537 @default.
- W3033870539 cites W1997485651 @default.
- W3033870539 cites W2003263727 @default.
- W3033870539 cites W2004483004 @default.
- W3033870539 cites W2006388642 @default.
- W3033870539 cites W2006441761 @default.
- W3033870539 cites W2007943477 @default.
- W3033870539 cites W2009458392 @default.
- W3033870539 cites W2009767499 @default.
- W3033870539 cites W2010558760 @default.
- W3033870539 cites W2014103593 @default.
- W3033870539 cites W2014947339 @default.
- W3033870539 cites W2023271753 @default.
- W3033870539 cites W2026965134 @default.
- W3033870539 cites W2028741942 @default.
- W3033870539 cites W2031596719 @default.
- W3033870539 cites W2038817840 @default.
- W3033870539 cites W2040891489 @default.
- W3033870539 cites W2051231673 @default.
- W3033870539 cites W2058210956 @default.
- W3033870539 cites W2060827063 @default.
- W3033870539 cites W2067335264 @default.
- W3033870539 cites W2069644546 @default.
- W3033870539 cites W2078146328 @default.
- W3033870539 cites W2079037572 @default.
- W3033870539 cites W2080118991 @default.
- W3033870539 cites W2083469020 @default.
- W3033870539 cites W2088253778 @default.
- W3033870539 cites W2088877194 @default.
- W3033870539 cites W2088964879 @default.
- W3033870539 cites W2090744162 @default.
- W3033870539 cites W2092777811 @default.
- W3033870539 cites W2093640671 @default.
- W3033870539 cites W2094565238 @default.
- W3033870539 cites W2094984922 @default.
- W3033870539 cites W2106243866 @default.
- W3033870539 cites W2110415648 @default.
- W3033870539 cites W2125085520 @default.
- W3033870539 cites W2136732881 @default.
- W3033870539 cites W2143981217 @default.
- W3033870539 cites W2159662109 @default.
- W3033870539 cites W2292519215 @default.
- W3033870539 cites W2331115690 @default.
- W3033870539 cites W2341795144 @default.
- W3033870539 cites W2416943959 @default.
- W3033870539 cites W2466739163 @default.
- W3033870539 cites W2527222280 @default.
- W3033870539 cites W2587395077 @default.
- W3033870539 cites W2590098501 @default.
- W3033870539 cites W2592354780 @default.
- W3033870539 cites W2599775531 @default.
- W3033870539 cites W2604185056 @default.
- W3033870539 cites W2611072627 @default.
- W3033870539 cites W2622877012 @default.
- W3033870539 cites W2747810633 @default.
- W3033870539 cites W2754301088 @default.
- W3033870539 cites W2789332714 @default.
- W3033870539 cites W2789519102 @default.
- W3033870539 cites W2791110498 @default.
- W3033870539 cites W2802275838 @default.
- W3033870539 cites W2825184923 @default.
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- W3033870539 cites W2898086608 @default.
- W3033870539 cites W2927106913 @default.
- W3033870539 cites W2940372771 @default.
- W3033870539 cites W2955848903 @default.
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- W3033870539 doi "https://doi.org/10.1016/j.molliq.2020.113508" @default.
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