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- W3033991039 abstract "A binary hybrid system comprising hypervalent iodine(III) reagent and BF3•OEt2 Lewis acid was found to be effective for the diastereoselective α-acetoxylation of cyclic ketones. In this hybrid system, BF3•OEt2 Lewis acid allowed the activation of hypervalent iodine (III) reagent and cyclic ketones for the smooth alpha-acetoxylation reaction, achieving high diastereoselectivity. This hypervalent iodine mediated α-acetoxylation of cyclic ketone reaction plausibly undergoes an SN2 substitution mechanism via α-C-bound hypervalent iodine intermediate. The diastereoselectivity of the reaction is mainly originated from thermodynamic control." @default.
- W3033991039 created "2020-06-12" @default.
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- W3033991039 date "2020-07-10" @default.
- W3033991039 modified "2023-10-16" @default.
- W3033991039 title "Hypervalent Iodine-Mediated Diastereoselective α-Acetoxylation of Cyclic Ketones" @default.
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- W3033991039 doi "https://doi.org/10.3389/fchem.2020.00467" @default.
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