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- W3034114541 abstract "The highly chemo- and enantioselective hydrogenation of (E)-2-substituted-4-oxo-2-alkenoic acids was established for the first time using the Rh/JosiPhos complex, affording a series of chiral α-substituted-γ-keto acids with excellent results (up to 99% yield and >99% ee) and high efficiency (up to 3000 TON). In addition, the importance of this methodology was further demonstrated by a concise and gram-scale synthesis of the anti-inflammatory drug (R)-flobufen." @default.
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- W3034114541 date "2020-06-10" @default.
- W3034114541 modified "2023-10-15" @default.
- W3034114541 title "Highly Chemo- and Enantioselective Hydrogenation of 2-Substituted-4-oxo-2-alkenoic Acids" @default.
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- W3034114541 doi "https://doi.org/10.1021/acs.orglett.0c01618" @default.
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