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- W3034383407 abstract "The reaction of copper nitrate with succinic acid (succH) and N , N , N ′, N ′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex catena -poly[[[( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)copper(II)]-μ-succinato-κ 2 O 1 : O 4 ] tetrahydrate], {[Cu(C 4 H 4 O 4 )(C 6 H 16 N 2 )]·4H 2 O} n or {[Cu(succ)(tmeda)]·4H 2 O} n . Each carboxylate group of the succinate ligand coordinates to a Cu II atom in a monodentate fashion, giving rise to a distorted square-planar geometry. The succinate ligands bridge the Cu II centres, forming one-dimensional polymeric chains. Hydrogen bonds between the ligands and water molecules link these chains into sheets that lie parallel to the ac plane. Hirshfeld surface analysis, d norm and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure." @default.
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- W3034383407 date "2020-06-09" @default.
- W3034383407 modified "2023-09-28" @default.
- W3034383407 title "Crystal structure and Hirshfeld surface analysis of one-dimensional copper(II) coordination polymer incorporating succinate and tetramethylethylenediamine ligands" @default.
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- W3034383407 doi "https://doi.org/10.1107/s2056989020007227" @default.
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