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- W3034467445 abstract "A complex ZnO/ZnAl 2 O 4 heterostructures thin films on glass and Si (111) substrates have been successively obtained by a soft ultrasonic spray pyrolysis (USP) method deposition using the Zn/Al molar ratios concentrations of 0.07/0.13 and 0.1/0.1, respectively. According to (XRD) an ordered zinc oxide (ZnO) and zinc aluminate (ZnAl 2 O 4 ) structures deposited onto glass from the air annealing at 500 °C during 2 hours was observed and confirmed by the (EDX), (FTIR) and Raman spectroscopy techniques. The estimated crystallites size and stress values of ZnO and ZnAl 2 O 4 in the ZnO/ZnAl 2 O 4 /glass film were 19 nm/0.469 GPa and 11 nm/-0.292 GPa, respectively. The lower Zn/Al molar ratio around 0.035/0.06 produced only ZnO as a single phase, suggesting the Al insufficient quantity. The Si (100) substrate with 0.07 Zn molarity conducted to the Zn 2 SiO 4 /ZnO/ZnAl 2 O 4 composite. The Raman integrated intensity bands of ZnO and ZnAl 2 O 4 increases with increasing Zn to Al molar ratio (0.1/0.1 comparatively to 0.07/0.13). The ZnO&ZnAl 2 O 4 crystallinity enhances as Zn molarity increases. The ZnO films in the composites grow with (002) texture. The TC( hkl ) value indicated that ZnAl 2 O 4 in the ZnO/ZnAl 2 O 4 /glass layer is polycrystalline preferentially oriented along the (311) plane. Spinel ZnAl 2 O 4 oxide onto Si (111) substrate grown according to the (220) orientation. Crystallites are larger in ZnO/ZnAl 2 O 4 /Si than in ZnO/ZnAl 2 O 4 /glass. The ZnO/ZnAl 2 O 4 film onto glass substrate is transparent in the visible and near infrared regions and sensitive to UV absorption, as characterized by UV-Vis spectroscopy. The ZnO and ZnAl 2 O 4 E g values in the ZnO/ZnAl 2 O 4 /glass composite were 3.25 and 3.88 eV, respectively." @default.
- W3034467445 created "2020-06-19" @default.
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- W3034467445 date "2020-06-01" @default.
- W3034467445 modified "2023-09-26" @default.
- W3034467445 title "Effect of Solution Concentration on ZnO/ZnAl<sub>2</sub>O<sub>4</sub> Nanocomposite Thin Films Formation Deposited by Ultrasonic Spray Pyrolysis on Glass and Si(111) Substrates" @default.
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- W3034467445 doi "https://doi.org/10.4028/www.scientific.net/jnanor.63.10" @default.
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