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- W3034880015 endingPage "4924" @default.
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- W3034880015 abstract "A novel method for facile postpolymerization functionalization of synthetic polymers using terminal norbornadiene (NBD) building blocks is presented. Incorporation of the NBD functionality streamlines the synthesis of a wide array of block polymers utilizing multistep click chemistry strategies. Previously, the use of NBD-functionalized initiators produced polymers that underwent a cascade of Diels–Alder (DA) reactions to unveil a reactive cyclopentadiene (Cp) chain end. When coupled with a maleimide-bearing counterpart, a highly efficient DA cycloaddition with the terminal Cp can occur. To extend this concept to a range of polyacrylates and commercially available poly(ethylene glycol) systems, we developed a novel NBD acid building block for postpolymerization functionalization. Employing this process, we have demonstrated straightforward access to a library of block polymers that leverage this NBD click platform." @default.
- W3034880015 created "2020-06-19" @default.
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- W3034880015 date "2020-06-11" @default.
- W3034880015 modified "2023-10-17" @default.
- W3034880015 title "Norbornadiene Chain-End Functional Polymers as Stable, Readily Available Precursors to Cyclopentadiene Derivatives" @default.
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- W3034880015 doi "https://doi.org/10.1021/acs.macromol.0c00967" @default.
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