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- W3035262445 endingPage "125052" @default.
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- W3035262445 abstract "The interplay between evaporation and liquid–liquid phase separation (demixing) in binary sessile drops of partially miscible liquids is investigated. To determine the onset of the demixing phenomenon, a simple model is developed, which predicts a considerable temperature reduction (∼20 °C) in the mixture due to evaporative cooling. Temperature reduction alongside with the change of composition lead to demixing in the mixtures. The model explains why a mixture at room temperature is able to demix, whilst the demixing upper critical temperature is at 6.3 °C. Five stages of the process are identified and explained. For the cases studied here, once the demixing begins through nucleation, a growing fingering pattern is formed at the contact line. The length of the fingers and the final area of deposition increase with the initial concentration. Experimental tests were performed using a double telecentric setup." @default.
- W3035262445 created "2020-06-19" @default.
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- W3035262445 date "2020-10-01" @default.
- W3035262445 modified "2023-09-30" @default.
- W3035262445 title "Evaporation induced demixing in binary sessile drops" @default.
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- W3035262445 doi "https://doi.org/10.1016/j.colsurfa.2020.125052" @default.
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