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- W3035277448 abstract "This study presents a facile high-yield bottom-up fabrication and morphology-structure investigations of a free-standing network of multi-layer quasi-2D flakes consisting of intrinsically nonlayered γ-Al2O3. The synthesis comprises a multi-cycle atomic layer deposition (ALD) of amorphous alumina that uses an interconnected graphene network as a growth scaffold followed by ≈800 °C air anneal. The structures are studied by X-ray diffraction, selected area electron diffraction, and high-resolution transmission electron microscopy, while electric properties are assessed with the help of two-terminal dc-transport measurements. The individual flakes comprise nanocrystalline phase cubic spinel γ-Al2O3 with a close-packed cubic texture in the 〈111〉cubic ALD-induced growth direction. The charge transport is confirmed to be Ohmic with the room temperature electrical conductivity approaching ≈10−8 S m−1. This work opens a door to a low-cost highly scalable synthesis of a variety of quasi-2D metal oxides for widespread uses ranging from support material, sensing to environmental remediation." @default.
- W3035277448 created "2020-06-19" @default.
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- W3035277448 date "2020-06-08" @default.
- W3035277448 modified "2023-09-23" @default.
- W3035277448 title "Quasi‐2D Crystalline γ‐Alumina Grown by Graphene‐Assisted Atomic Layer Deposition" @default.
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- W3035277448 doi "https://doi.org/10.1002/admi.202000561" @default.
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