Matches in SemOpenAlex for { <https://semopenalex.org/work/W3035489211> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W3035489211 abstract "Glycerol is a byproduct of biodiesel production and an abundant feedstock for the synthesis of high-value chemicals. A promising approach for valorization of glycerol is electrooxidation on gold. In this work, we investigate electrooxidation of glycerol on gold in acidic media using cyclic voltammetry and density functional theory calculations. Experimentally, we observe activity for electrooxidation above a potential of 0.5 V versus the reversible hydrogen electrode (RHE). A Pourbaix diagram is calculated to evaluate the surface coverage under reaction conditions, indicating that the surface is free from adsorbates at the measured onset potential. Computationally, we find that the onset potentials for partial dehydrogenation of glycerol to dihydroxyacetone, 2,3-dihydroxy-2-propenal, and glyceraldehyde are 0.39, 0.39, and 0.60 V versus RHE, respectively, while complete dehydrogenation to carbon monoxide requires 0.50 V versus RHE. Our theoretical and experimental findings are in agreement and show the possibility of using gold as a catalyst for the production of hydrogen and other valuable chemicals from glycerol." @default.
- W3035489211 created "2020-06-19" @default.
- W3035489211 creator A5010656025 @default.
- W3035489211 creator A5034924108 @default.
- W3035489211 creator A5041128128 @default.
- W3035489211 creator A5058183169 @default.
- W3035489211 creator A5079581026 @default.
- W3035489211 creator A5079828388 @default.
- W3035489211 date "2018-01-01" @default.
- W3035489211 modified "2023-09-28" @default.
- W3035489211 title "Electrooxidation of Glycerol on Gold in Acidic Medium: A Combined Experimental and DFT Study C" @default.
- W3035489211 hasPublicationYear "2018" @default.
- W3035489211 type Work @default.
- W3035489211 sameAs 3035489211 @default.
- W3035489211 citedByCount "0" @default.
- W3035489211 crossrefType "journal-article" @default.
- W3035489211 hasAuthorship W3035489211A5010656025 @default.
- W3035489211 hasAuthorship W3035489211A5034924108 @default.
- W3035489211 hasAuthorship W3035489211A5041128128 @default.
- W3035489211 hasAuthorship W3035489211A5058183169 @default.
- W3035489211 hasAuthorship W3035489211A5079581026 @default.
- W3035489211 hasAuthorship W3035489211A5079828388 @default.
- W3035489211 hasConcept C119889771 @default.
- W3035489211 hasConcept C147789679 @default.
- W3035489211 hasConcept C161790260 @default.
- W3035489211 hasConcept C17525397 @default.
- W3035489211 hasConcept C178790620 @default.
- W3035489211 hasConcept C179104552 @default.
- W3035489211 hasConcept C181199279 @default.
- W3035489211 hasConcept C185592680 @default.
- W3035489211 hasConcept C2776317432 @default.
- W3035489211 hasConcept C2777869211 @default.
- W3035489211 hasConcept C2779735320 @default.
- W3035489211 hasConcept C2780881558 @default.
- W3035489211 hasConcept C2781272698 @default.
- W3035489211 hasConcept C512735826 @default.
- W3035489211 hasConcept C512968161 @default.
- W3035489211 hasConcept C52859227 @default.
- W3035489211 hasConcept C52896960 @default.
- W3035489211 hasConcept C66910140 @default.
- W3035489211 hasConceptScore W3035489211C119889771 @default.
- W3035489211 hasConceptScore W3035489211C147789679 @default.
- W3035489211 hasConceptScore W3035489211C161790260 @default.
- W3035489211 hasConceptScore W3035489211C17525397 @default.
- W3035489211 hasConceptScore W3035489211C178790620 @default.
- W3035489211 hasConceptScore W3035489211C179104552 @default.
- W3035489211 hasConceptScore W3035489211C181199279 @default.
- W3035489211 hasConceptScore W3035489211C185592680 @default.
- W3035489211 hasConceptScore W3035489211C2776317432 @default.
- W3035489211 hasConceptScore W3035489211C2777869211 @default.
- W3035489211 hasConceptScore W3035489211C2779735320 @default.
- W3035489211 hasConceptScore W3035489211C2780881558 @default.
- W3035489211 hasConceptScore W3035489211C2781272698 @default.
- W3035489211 hasConceptScore W3035489211C512735826 @default.
- W3035489211 hasConceptScore W3035489211C512968161 @default.
- W3035489211 hasConceptScore W3035489211C52859227 @default.
- W3035489211 hasConceptScore W3035489211C52896960 @default.
- W3035489211 hasConceptScore W3035489211C66910140 @default.
- W3035489211 hasLocation W30354892111 @default.
- W3035489211 hasOpenAccess W3035489211 @default.
- W3035489211 hasPrimaryLocation W30354892111 @default.
- W3035489211 hasRelatedWork W1628214 @default.
- W3035489211 hasRelatedWork W1970619440 @default.
- W3035489211 hasRelatedWork W1974856176 @default.
- W3035489211 hasRelatedWork W1980977143 @default.
- W3035489211 hasRelatedWork W2033042113 @default.
- W3035489211 hasRelatedWork W2097226993 @default.
- W3035489211 hasRelatedWork W2136741165 @default.
- W3035489211 hasRelatedWork W2160384251 @default.
- W3035489211 hasRelatedWork W2335641101 @default.
- W3035489211 hasRelatedWork W2360398169 @default.
- W3035489211 hasRelatedWork W2426612584 @default.
- W3035489211 hasRelatedWork W2515653838 @default.
- W3035489211 hasRelatedWork W2762056587 @default.
- W3035489211 hasRelatedWork W2771933970 @default.
- W3035489211 hasRelatedWork W2900404791 @default.
- W3035489211 hasRelatedWork W2916955809 @default.
- W3035489211 hasRelatedWork W2924522669 @default.
- W3035489211 hasRelatedWork W2990258845 @default.
- W3035489211 hasRelatedWork W3091171288 @default.
- W3035489211 hasRelatedWork W3158552190 @default.
- W3035489211 isParatext "false" @default.
- W3035489211 isRetracted "false" @default.
- W3035489211 magId "3035489211" @default.
- W3035489211 workType "article" @default.