Matches in SemOpenAlex for { <https://semopenalex.org/work/W3035663323> ?p ?o ?g. }
- W3035663323 endingPage "118295" @default.
- W3035663323 startingPage "118295" @default.
- W3035663323 abstract "Highly active Co/ZrO2 catalysts were synthesized for the conversion of ethyl palmitate to alcohol or diesel-like alkanes, with high yield and tunable selectivity, controlled by reaction temperature. The formation of hexadecanol was favored at lower temperatures, while higher temperatures promoted the formation of alkanes. Over 15Co/ZrO2, the highest yield of alkanes (~82%) was achieved at 240 °C, 8 h, while the highest yield of 1-hexadecanol (85.7%) was obtained at 200 °C, 24 h. The dominant pathway for the formation of alkanes proceeded via hydrogenation to aldehyde, followed by decarbonylation to Cn-1 alkane, accompanied by small fraction of total hydrodeoxygenation to Cn alkane and cracking to shorter-chain alkanes. The decrease in reaction temperature blocked the decarbonylation and hydrodeoxygenation routes, generating hexadecanol from hexadecanal with high yield and selectivity by prolonging the reaction time. The deoxygenation of ethyl palmitate was synergistically catalyzed by the Co site and oxygen deficient ZrO2 site." @default.
- W3035663323 created "2020-06-19" @default.
- W3035663323 creator A5005325749 @default.
- W3035663323 creator A5022746945 @default.
- W3035663323 creator A5071417968 @default.
- W3035663323 creator A5079526395 @default.
- W3035663323 date "2020-10-01" @default.
- W3035663323 modified "2023-10-16" @default.
- W3035663323 title "Temperature-tuned selectivity to alkanes or alcohol from ethyl palmitate deoxygenation over zirconia-supported cobalt catalyst" @default.
- W3035663323 cites W1916148586 @default.
- W3035663323 cites W1969942997 @default.
- W3035663323 cites W1973559036 @default.
- W3035663323 cites W1984348417 @default.
- W3035663323 cites W1990357763 @default.
- W3035663323 cites W2002028196 @default.
- W3035663323 cites W2007624026 @default.
- W3035663323 cites W2008920106 @default.
- W3035663323 cites W2010685748 @default.
- W3035663323 cites W2011204692 @default.
- W3035663323 cites W2011835332 @default.
- W3035663323 cites W2025094152 @default.
- W3035663323 cites W2028919531 @default.
- W3035663323 cites W2041809110 @default.
- W3035663323 cites W2043914351 @default.
- W3035663323 cites W2066270075 @default.
- W3035663323 cites W2071107872 @default.
- W3035663323 cites W2083416653 @default.
- W3035663323 cites W2086529313 @default.
- W3035663323 cites W2090802494 @default.
- W3035663323 cites W2092400267 @default.
- W3035663323 cites W2114843659 @default.
- W3035663323 cites W2158651823 @default.
- W3035663323 cites W2173423832 @default.
- W3035663323 cites W2184778329 @default.
- W3035663323 cites W2265047766 @default.
- W3035663323 cites W2292504714 @default.
- W3035663323 cites W2293044860 @default.
- W3035663323 cites W2416162415 @default.
- W3035663323 cites W2428220922 @default.
- W3035663323 cites W2438027884 @default.
- W3035663323 cites W2484233002 @default.
- W3035663323 cites W2509869834 @default.
- W3035663323 cites W2511452911 @default.
- W3035663323 cites W2513704500 @default.
- W3035663323 cites W2521314152 @default.
- W3035663323 cites W2592151008 @default.
- W3035663323 cites W2604956736 @default.
- W3035663323 cites W2611258516 @default.
- W3035663323 cites W2613668276 @default.
- W3035663323 cites W2741474199 @default.
- W3035663323 cites W2776851694 @default.
- W3035663323 cites W2778844521 @default.
- W3035663323 cites W2789461104 @default.
- W3035663323 cites W2809286430 @default.
- W3035663323 cites W2811501868 @default.
- W3035663323 cites W2848908709 @default.
- W3035663323 cites W2901628235 @default.
- W3035663323 cites W2902470759 @default.
- W3035663323 cites W2903077926 @default.
- W3035663323 cites W2929784144 @default.
- W3035663323 cites W2940407238 @default.
- W3035663323 cites W2943897925 @default.
- W3035663323 cites W2948353437 @default.
- W3035663323 cites W2967859783 @default.
- W3035663323 cites W2968830753 @default.
- W3035663323 cites W2971014800 @default.
- W3035663323 cites W2972779390 @default.
- W3035663323 cites W2992070538 @default.
- W3035663323 cites W4235816322 @default.
- W3035663323 doi "https://doi.org/10.1016/j.fuel.2020.118295" @default.
- W3035663323 hasPublicationYear "2020" @default.
- W3035663323 type Work @default.
- W3035663323 sameAs 3035663323 @default.
- W3035663323 citedByCount "26" @default.
- W3035663323 countsByYear W30356633232021 @default.
- W3035663323 countsByYear W30356633232022 @default.
- W3035663323 countsByYear W30356633232023 @default.
- W3035663323 crossrefType "journal-article" @default.
- W3035663323 hasAuthorship W3035663323A5005325749 @default.
- W3035663323 hasAuthorship W3035663323A5022746945 @default.
- W3035663323 hasAuthorship W3035663323A5071417968 @default.
- W3035663323 hasAuthorship W3035663323A5079526395 @default.
- W3035663323 hasConcept C118792377 @default.
- W3035663323 hasConcept C132190689 @default.
- W3035663323 hasConcept C134121241 @default.
- W3035663323 hasConcept C161790260 @default.
- W3035663323 hasConcept C178790620 @default.
- W3035663323 hasConcept C185592680 @default.
- W3035663323 hasConcept C191897082 @default.
- W3035663323 hasConcept C192562407 @default.
- W3035663323 hasConcept C2778496505 @default.
- W3035663323 hasConcept C2779778602 @default.
- W3035663323 hasConcept C2779825165 @default.
- W3035663323 hasConcept C2781066024 @default.
- W3035663323 hasConcept C2781327020 @default.
- W3035663323 hasConcept C515602321 @default.
- W3035663323 hasConceptScore W3035663323C118792377 @default.
- W3035663323 hasConceptScore W3035663323C132190689 @default.