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- W3035758756 abstract "Artificial bases have emerged as a useful tool to expand genetic alphabets and biomedical applications of oligonucleotides. Herein, we reported that the conformation conversion enhances cellular uptake of hydrophobic 3,5-bis(trifluoromethyl)benzene (F) base double-strand-conjugated oligonucleotides. The formation of the F base double-strand caged the hydrophobic F base in the duplex strand, thus preventing F base from interacting with cells to some extent. However, upon conversion of F base double-strand-conjugated oligonucleotide to F base single-strand-conjugated oligonucleotide, F bases then were allowed to interact with cells by stronger hydrophobic interactions, followed by cellular uptake. The results were concluded as a pairing-induced cage effect of F base and have the potential for the construction of stimuli-responsive cellular uptake of functional nucleic acids." @default.
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- W3035758756 date "2020-06-12" @default.
- W3035758756 modified "2023-10-18" @default.
- W3035758756 title "Conformational Conversion Enhances Cellular Uptake of F Base Double-Strand-Conjugated Oligonucleotides" @default.
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- W3035758756 doi "https://doi.org/10.1021/acs.analchem.0c00614" @default.
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