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- W3036202413 abstract "Nanostructured zeolites are ubiquitous throughout chemistry as catalysts and sorption media' A new variety of zeolites, constructed by templating inorganic silica on surfactant liquid crystalline phases, consist of ordered arrays of cylindrical pores with diameters ranging from 20 Å to greater than 500 Å. The nanostructure of these materials can be tailored to a variety of applications, each of which makes use of the zeolite network's large surface area and prescribed microstructure. Recent studies indicate that the initial step in the nanophase formation is a cooperative self-assembly of inorganic silicate species and organic surfactant species, dictated by ionic interaction between silicate anions and cationic surfactants. Freeze-fracture transmission electron microscopy (FF-TEM) is the only technique that can visualize this self-assembly process in situ to determine phase boundaries and examine the formation mechanism. The nanophases form on mixing aqueous cetyl trimethylammonium bromide (CTAB) with silicate (SiO 2 ; prepared from CAB-O-SIL M-5, tetramethylammonium hydroxide (TMA-OH), trimethyl benzene (TMB), methanol (CH 3 OH), and water)." @default.
- W3036202413 created "2020-06-25" @default.
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- W3036202413 date "1995-08-13" @default.
- W3036202413 modified "2023-09-26" @default.
- W3036202413 title "Self-assembly of surfactant-silicate nanophases" @default.
- W3036202413 cites W1987334490 @default.
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- W3036202413 doi "https://doi.org/10.1017/s0424820100137276" @default.
- W3036202413 hasPublicationYear "1995" @default.
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