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- W3036280407 abstract "Abstract The first total synthesis of terpioside B ( 1 ) has been accomplished. Key steps include the stereoselective installments of a set of challenging 1,2‐ cis ‐glycosidic linkages. Thus, α(1,4)‐linked d ‐galactoside was effectively constructed from a 1,2‐anhydrogalactose donor and an unprotected 1,6‐anhydrogalactose acceptor by using a boron‐mediated aglycon delivery (BMAD) method. In addition, α‐ l ‐fucofuranosides were stereoselectively and simultaneously constructed by remote group‐assisted 1,2‐ cis ‐α‐stereoselective glycosylations." @default.
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- W3036280407 date "2020-07-13" @default.
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- W3036280407 title "Total Synthesis of Terpioside B" @default.
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- W3036280407 doi "https://doi.org/10.1002/chem.202002878" @default.
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