FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3036306570> ?p ?o ?g. }

• W3036306570 endingPage "4348" @default.
• W3036306570 startingPage "4342" @default.
• W3036306570 abstract "The crystal structure at room temperature and the low-temperature heat capacity and magnetic susceptibilities of single crystals of [${(mathrm{C}{mathrm{H}}_{3})}_{3}$ NH]Cu${mathrm{Cl}}_{3}$ ifmmodecdotelsetextperiodcenteredfi{} 2${mathrm{H}}_{2}$O are reported. The monoclinic crystals belong to the space group $frac{P{2}_{1}}{c}$ with $a=7.479(10)$ AA{}, $b=7.864(11)$ AA{}, $c=16.730(23)$ AA{}, $ensuremath{beta}=91.98(3)ifmmode^circelsetextdegreefi{}$, and $Z=4$. The structure consists of chains of edge-sharing [Cu${mathrm{Cl}}_{4}$${(mathrm{O}{mathrm{H}}_{2})}_{2}$] octahedra running along the $a$ axis. Each copper atom is coordinated in a square plane by two water molecules and two chlorine atoms, with two more chlorine atoms at a longer distance. The susceptibility data can be fitted adequately between 1.5 and 20 ifmmode^circelsetextdegreefi{}K by a Curie---Weiss law [${g}_{a}=2.08ifmmodepmelsetextpmfi{}0.01$, ${g}_{b}=2.02ifmmodepmelsetextpmfi{}0.01$; ${g}_{{c}^{ensuremath{'}}}=2.11ifmmodepmelsetextpmfi{}0.01$; ${ensuremath{theta}}_{a}=(0.38ifmmodepmelsetextpmfi{}0.03)ifmmode^circelsetextdegreefi{}$K, ${ensuremath{theta}}_{b}=(0.36ifmmodepmelsetextpmfi{}0.03)ifmmode^circelsetextdegreefi{}$K, ${ensuremath{theta}}_{{c}^{ensuremath{'}}}=(0.41ifmmodepmelsetextpmfi{}0.03)ifmmode^circelsetextdegreefi{}$K], but the susceptibility parallel to the chain can be better fitted as an Ising linear chain. Measurements perpendicular to the chain are not as well fitted by the Ising model. The heat capacity, which consists primarily of a lattice contribution above 3 ifmmode^circelsetextdegreefi{}K, begins to rise as the temperature falls below 3 ifmmode^circelsetextdegreefi{}K, but long-range order does not set in above 1 ifmmode^circelsetextdegreefi{}K, the lowest temperature attained in this work. Both Ising and Heisenberg linear-chain models fit the low-temperature data with $|frac{J}{k}| <1ifmmode^circelsetextdegreefi{}$K. The results are compared with those reported for the compounds Cu${mathrm{Cl}}_{2}$ ifmmodecdotelsetextperiodcenteredfi{} 2${mathrm{H}}_{2}$O and Cu${mathrm{Cl}}_{2}$ ifmmodecdotelsetextperiodcenteredfi{} 2N${mathrm{C}}_{5}$${mathrm{H}}_{5}$." @default.
• W3036306570 created "2020-06-25" @default.
• W3036306570 creator A5012211649 @default.
• W3036306570 creator A5017479289 @default.
• W3036306570 creator A5018154474 @default.
• W3036306570 creator A5049574238 @default.
• W3036306570 creator A5058435329 @default.
• W3036306570 creator A5061311265 @default.
• W3036306570 creator A5077631274 @default.
• W3036306570 date "1972-12-01" @default.
• W3036306570 modified "2023-09-26" @default.
• W3036306570 title "Structural and Magnetic Properties of [<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi mathvariant=normal>C</mml:mi><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>H</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>NH] Cu<mml:math xmlns:mml=http://www.w3.org/1998/Math/…" @default.
• W3036306570 cites W1491377492 @default.
• W3036306570 cites W1510048840 @default.
• W3036306570 cites W1550283778 @default.
• W3036306570 cites W1638186760 @default.
• W3036306570 cites W1966983497 @default.
• W3036306570 cites W1992066112 @default.
• W3036306570 cites W2018235187 @default.
• W3036306570 cites W2027913167 @default.
• W3036306570 cites W2028109127 @default.
• W3036306570 cites W2033034088 @default.
• W3036306570 cites W2038750483 @default.
• W3036306570 cites W2049749977 @default.
• W3036306570 cites W2051858385 @default.
• W3036306570 cites W2060797799 @default.
• W3036306570 cites W2069632511 @default.
• W3036306570 cites W2077086161 @default.
• W3036306570 cites W2080237020 @default.
• W3036306570 cites W2091309251 @default.
• W3036306570 cites W2111125927 @default.
• W3036306570 cites W2354978257 @default.
• W3036306570 cites W2368758622 @default.
• W3036306570 cites W2580711636 @default.
• W3036306570 cites W2735806552 @default.
• W3036306570 cites W4230153162 @default.
• W3036306570 cites W4251233955 @default.
• W3036306570 doi "https://doi.org/10.1103/physrevb.6.4342" @default.
• W3036306570 hasPublicationYear "1972" @default.
• W3036306570 type Work @default.
• W3036306570 sameAs 3036306570 @default.
• W3036306570 citedByCount "32" @default.
• W3036306570 crossrefType "journal-article" @default.
• W3036306570 hasAuthorship W3036306570A5012211649 @default.
• W3036306570 hasAuthorship W3036306570A5017479289 @default.
• W3036306570 hasAuthorship W3036306570A5018154474 @default.
• W3036306570 hasAuthorship W3036306570A5049574238 @default.
• W3036306570 hasAuthorship W3036306570A5058435329 @default.
• W3036306570 hasAuthorship W3036306570A5061311265 @default.
• W3036306570 hasAuthorship W3036306570A5077631274 @default.
• W3036306570 hasConcept C114614502 @default.
• W3036306570 hasConcept C115624301 @default.
• W3036306570 hasConcept C121332964 @default.
• W3036306570 hasConcept C185592680 @default.
• W3036306570 hasConcept C198819137 @default.
• W3036306570 hasConcept C33923547 @default.
• W3036306570 hasConcept C61276311 @default.
• W3036306570 hasConcept C8010536 @default.
• W3036306570 hasConceptScore W3036306570C114614502 @default.
• W3036306570 hasConceptScore W3036306570C115624301 @default.
• W3036306570 hasConceptScore W3036306570C121332964 @default.
• W3036306570 hasConceptScore W3036306570C185592680 @default.
• W3036306570 hasConceptScore W3036306570C198819137 @default.
• W3036306570 hasConceptScore W3036306570C33923547 @default.
• W3036306570 hasConceptScore W3036306570C61276311 @default.
• W3036306570 hasConceptScore W3036306570C8010536 @default.
• W3036306570 hasIssue "11" @default.
• W3036306570 hasLocation W30363065701 @default.
• W3036306570 hasOpenAccess W3036306570 @default.
• W3036306570 hasPrimaryLocation W30363065701 @default.
• W3036306570 hasRelatedWork W1969352129 @default.
• W3036306570 hasRelatedWork W2026605788 @default.
• W3036306570 hasRelatedWork W2040850106 @default.
• W3036306570 hasRelatedWork W2082278137 @default.
• W3036306570 hasRelatedWork W2087080763 @default.
• W3036306570 hasRelatedWork W2097225352 @default.
• W3036306570 hasRelatedWork W2360958765 @default.
• W3036306570 hasRelatedWork W2462612165 @default.
• W3036306570 hasRelatedWork W2950660506 @default.
• W3036306570 hasRelatedWork W2950420198 @default.
• W3036306570 hasVolume "6" @default.
• W3036306570 isParatext "false" @default.
• W3036306570 isRetracted "false" @default.
• W3036306570 magId "3036306570" @default.
• W3036306570 workType "article" @default.