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- W3036473360 endingPage "131342" @default.
- W3036473360 startingPage "131342" @default.
- W3036473360 abstract "A novel copper-catalyzed sp3-carbon radical/carbamoyl radical cross-coupling protocol for the construction of C(sp3)-C(O) bond is described. This provides a straightforward method for synthesis of 2-carbamoyl-1,3-dicarbonyl compounds in good to excellent yields under mild conditions. Mechanistic studies confirms the generation of both carbamoyl and C(sp3)-centered radicals directly from oxidation of C(sp3)-H bond of formamides and 1,3-dicarbonyl compounds, respectively." @default.
- W3036473360 created "2020-06-25" @default.
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- W3036473360 date "2020-07-01" @default.
- W3036473360 modified "2023-10-18" @default.
- W3036473360 title "Copper-catalyzed sp3-carbon radical/carbamoyl radical cross coupling: A direct strategy for carbamoylation of 1,3-dicarbonyl compounds" @default.
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- W3036473360 doi "https://doi.org/10.1016/j.tet.2020.131342" @default.
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