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• W3036559715 abstract "Abstract Herein, we describe the first total synthesis of (+)‐cornexistin as well as its 8‐ epi ‐isomer starting from malic acid. The robust and scalable route features a Nozaki–Hiyama–Kishi reaction, an auxiliary‐controlled syn ‐Evans‐aldol reaction, and a highly efficient intramolecular alkylation to form the nine‐membered carbocycle. The delicate maleic anhydride moiety of the nonadride skeleton was constructed from a β‐keto nitrile. The developed route enabled the synthesis of 165 mg (+)‐cornexistin." @default.
• W3036559715 created "2020-06-25" @default.
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• W3036559715 date "2020-08-18" @default.
• W3036559715 modified "2023-09-26" @default.
• W3036559715 title "Total Synthesis of (+)‐Cornexistin" @default.
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• W3036559715 doi "https://doi.org/10.1002/anie.202008158" @default.
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