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- W3036699019 abstract "Displacement of oil droplets receding from solid surfaces in aqueous solutions plays a critical role in many household activities and industrial operations. Surfactants are often involved in these activities to control the displacement process. We hypothesize that the influence of surfactants on the displacement process of oil is highly dependent on the type and dosage of surfactants, with the mechanisms being elucidated by the analysis using appropriate dynamic wetting models. We systematically investigated the spontaneous displacement of a high viscosity oil on curved hydrophilic glass surfaces in aqueous solutions of anionic sodium dodecylbenzene sulfonate, cationic hexadecyl trimethyl ammonium bromide, and nonionic TritonTM X-100 over a wide range of concentrations. The rather different oil displacement behaviors were observed with different surfactant additions. The displacement dynamics of the receding oil droplet was found to be inhibited by surfactant additions and followed two distinct models quantitatively: the power-law model describing the temporal evolution of early-stage displacement, and the molecular kinetic model describing the dependence of the three-phase contact line displacement velocity on the dynamic contact angle at the late stage of oil displacement. The model-based data analysis provided insights on the role of surfactants in controlling the oil displacement dynamics." @default.
- W3036699019 created "2020-06-25" @default.
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- W3036699019 date "2020-11-01" @default.
- W3036699019 modified "2023-10-17" @default.
- W3036699019 title "Role of surfactants in spontaneous displacement of high viscosity oil droplets from solid surfaces in aqueous solutions" @default.
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- W3036699019 doi "https://doi.org/10.1016/j.jcis.2020.06.069" @default.
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- W3036699019 hasPublicationYear "2020" @default.
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