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- W3036779750 abstract "Direct intramolecular aminoboration of sulfonamidoallenes was realized using BCl3 as a boron source. The reactions benefited from the interaction between BCl3 and sulfonamides and provided a variety of borylvinyl heterocycles in good isolated yields. When chiral substrates were involved in the reactions, high stereoselectivity was observed, as can be ascertained by single-crystal X-ray diffraction experiments. Derivatization of the thus-obtained borylvinyl compounds proceeded readily, and different functionalities could be obtained via oxidation, halogenation, and Suzuki coupling reactions." @default.
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- W3036779750 date "2020-06-19" @default.
- W3036779750 modified "2023-10-15" @default.
- W3036779750 title "Direct Intramolecular Aminoboration of Allenes" @default.
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- W3036779750 doi "https://doi.org/10.1021/acs.orglett.0c01685" @default.
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