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• W3036802188 endingPage "128697" @default.
• W3036802188 startingPage "128697" @default.
• W3036802188 abstract "Removal of toxic nitroarenes, which threaten all living organisms and environment, from wastewaters has been an important and prior issue. Therefore, the focus of the present study was to fabricate an effective, fast, reusable, and easily recoverable heterogeneous Pd nanoparticles (Pd NPs) supported on a novel polyazomethine having phenol group (Pd [email protected] P(3-M-4-PAP)) for removal of several hazardous nitroarenes by catalytic reduction from water. Firstly, a novel polyazomethine featuring phenol group was prepared as a stabilizer and then, Pd NPs were anchored on it. Characterizations of the materials were performed by XRD, UV–Vis, FTIR, 1H-NMR, TGA, FE-SEM, EDS and TEM techniques. The obtained TEM analysis results showed that the size of Pd NPs was about 50 nm. Then, catalytic ability of Pd [email protected](3-M-4-PAP) was investigated in reduction of harmful nitroarenes to useful aniline derivatives in water. Catalytic tests revealed that Pd [email protected](3-M-4-PAP) had outstanding catalytic efficiency against reduction of different nitroarenes by giving excellent yields (up to 98%), in very short time (between 22s and 70s) with 2 mg nanocatalyst. Moreover, performed reusability test results demonstrated that the Pd [email protected](3-M-4-PAP) could be recurrently reusable and easily recoverable." @default.
• W3036802188 created "2020-06-25" @default.
• W3036802188 creator A5074728254 @default.
• W3036802188 date "2020-11-01" @default.
• W3036802188 modified "2023-10-01" @default.
• W3036802188 title "Generation and characterization of palladium nanocatalyst anchored on a novel polyazomethine support: Application in highly efficient and quick catalytic reduction of environmental contaminant nitroarenes" @default.
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• W3036802188 doi "https://doi.org/10.1016/j.molstruc.2020.128697" @default.
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