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• W3036903574 abstract "The ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) using phosphorus pentoxide (P2O5) as a metal-free catalyst and isopropanol (iPrOH) as initiator resulted in the preparation of poly(ε-caprolactone) with narrow weight distribution. NMR spectroscopy analyses of the prepared PCL indicated the presence of the initiator residue at the end of the polymer chain, implying the occurrence of the ε-CL-catalysis ROP through a monomer activation mechanism. Kinetic experiments confirmed the controlled/living nature of ε-CL ring-opening catalyzed by phosphorus pentoxide. The commercial availability of phosphorus pentoxide and its easy-handling provide additional opportunities for polymer synthesis and nanocomposite manufacturing." @default.
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• W3036903574 date "2020-01-01" @default.
• W3036903574 modified "2023-09-30" @default.
• W3036903574 title "Phosphorus pentoxide as a cost-effective, metal-free catalyst for ring opening polymerization of ε-caprolactone" @default.
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• W3036903574 doi "https://doi.org/10.1039/d0ra04251j" @default.
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