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- W3037097997 abstract "Previously, it has been demonstrated that external electric fields may be used to exert control over chemical reactivity. In this study, the impact of a strong, nonresonant IR field (1064 nm) on the photoisomerization of cis-stilbene is investigated in cyclohexane solution. The design of a suitable reaction vessel for characterization of this effect is presented. The electric field supplied by the pulsed, near-IR radiation (εl = 4.5 × 107 V/cm) enhances the cis → trans photoisomerization yield at the red edge of the absorption spectrum (wavelengths between 337 and 340 nm). Within the microliter focal volume, up to 75% of all cis-stilbene molecules undergo isomerization to trans-stilbene in the strong electric-field environment, indicating a significant increase relative to the 35% yield of trans-stilbene under field-free conditions. This result correlates with a 1-3% enhancement in the trans-stilbene concentration throughout the bulk solution. Theoretical analysis suggests that the observed change is the result of dynamic Stark shifting of the ground and first excited states, leading to a significant redshift in cis-stilbene's absorption spectrum. The predicted increase in the absorption cross section in this range of excitation wavelengths is qualitatively consistent with the experimental increase in trans-stilbene production." @default.
- W3037097997 created "2020-07-02" @default.
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- W3037097997 date "2020-06-25" @default.
- W3037097997 modified "2023-09-27" @default.
- W3037097997 title "Strong, Nonresonant Radiation Enhances <i>Cis</i>–<i>Trans</i> Photoisomerization of Stilbene in Solution" @default.
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- W3037097997 doi "https://doi.org/10.1021/acs.jpca.0c02732" @default.
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