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- W3037187450 abstract "Abstract The present work is focused on the understanding of the CeO 2 support interactions with cyclodextrin‐stabilized palladium nanoparticles (PdNPs) and the effect in the Suzuki‐Miyaura reaction outcome. Mostly, it is evidenced the strong influence of the cyclodextrin torus on the reactivity of PdNPs towards the ceria matrix. Structural characterization by X‐rays photoelectron spectroscopy (XPS) Raman spectroscopy, diffuse reflectance spectroscopy (DRS) and powder X‐rays diffraction (XRD, via Rietveld refinement) afforded to infer that palladium is being partially brought into the CeO 2 structure. Transmission electron microscopies (TEM and STEM) visualizations allowed to evidence a bimodal size distribution of PdNPs (1–5 nm and 20–100 nm) over the catalysts even though particles up to 5 nm are probably the most responsible for the catalytic results reported herein." @default.
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- W3037187450 date "2020-06-26" @default.
- W3037187450 modified "2023-10-14" @default.
- W3037187450 title "Cyclodextrin ‐ Stabilized Palladium Nanoparticles on Ceria: Investigation of Support Interactions and Pivotal Promotion in the Suzuki‐Miyaura Reaction" @default.
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- W3037187450 doi "https://doi.org/10.1002/slct.202001981" @default.
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